论文中英文摘要格式.docVIP

附件2： 论文中英文摘要格式 作者姓名：论文题目： 作者简介：中 文 摘 要 关键词：Structure and Negative Thermal Expansion in the Lead Titanate-Based Compounds Jun Chen ABSTRACT Lead titanate (PbTiO3) is one of important perovskite-type ferroelectrics which has been widely investigated and applied in the field of dielectric, piezoelectricity, ferroelectricity and pyroelectricity. Furthermore, PbTiO3 behaves a novel thermal property, that is negative thermal expansion (NTE), whose unit cell volume contracts on heating in the temperature range of room temperature to the Curie point (TC). The NTE property of PbTiO3 is very different with almost all other numbers of perovskites, such as CaTiO3, BaTiO3, KNbO3 and BiFeO3. The investigations on the NTE of PbTiO3 will be helpful for the control of NTE, design of zero thermal expansion (ZTE) materials and exploitation of the NTE materials application. Additionally, the NTE mechanism of PbTiO3 would be applied for the design of new NTE materials. In the present dissertation, the perovskite-type ferroelectrics Pb1-xAxTi1-yByO3 (A = La, Sr, Cd, Bi, (La1/2K1/2); B = Fe, Zn) were selected to investigate the A and B-site substitution dependence of NTE, crystal structure and lattice dynamics, so as to realize the control of NTE, exploit ZTE materials, and study the mechanism of NTE of PbTiO3. In the Pb1-xAxTiO3 (A = La, Sr, (La1/2K1/2) and Cd) compounds, the properties of solubility, crystal structure and NTE were investigated. The substitution of Pb by La, Sr and (La1/2K1/2) reduces the tetrogonality (c/a) and the Curie temperature linearly. The NTE is reduced dramatically by La doping in PbTiO3, and Pb1-xLaxTiO3 compounds exhibit ZTE in the solubility range of 0.15 ≤ xLa ≤ 0.20. For the PbTiO3-CdTiO3, the substitution of Pb by Cd not only increases the c/a ratio but also enhances the NTE, which is only found that can raise both the tetragonality and the NTE in the A-site doped PbTiO3 up to now. As for the crystal structures of Pb1-3/2xLaxTiO3, the atom displace