酸性硫酸盐电解液中沉积Ni-W合金的动力学研究.docVIP

酸性硫酸盐电解液中沉积Ni-W合金的动力学研究 刘慧娟1，张平2，周琼宇1，李珂1，钟庆东*1 1（上海大学 上海市现代冶金与材料制备重点实验室 上海 200072） 2（四川省电力公司遂宁公司 四川 629000） 摘要: 本文在酸性硫酸盐镀液中，采用循环伏安曲线和多电位阶跃等电化学分析方法结合Scharifker-Hills模型对Ni-W合金镀层的沉积过程进行了动力学研究。结果表明：Ni-W合金循环伏安曲线存在电流环，在玻碳电极上发生成核过程；电解液中WO4-浓度增加促进形核在玻碳电极上表现为三维生长的成核机理WO42-进行Ni-W合金在, 在较大的过电位下略有与连续形核曲线略有偏离，表现为连续形核和瞬时形核共存的形核机制。 关键词：Ni–W合金；； Kinetics analysis of Ni-W alloy electro-deposition in acidic sulphate electrolyte LIU Hui-juan1, ZHANG Ping1, ZHOU Qiong-yu1, LI Ke1, ZHONG Qing-dong*1 1 (Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072, China) 2（Sichuan Electric Power Corporation Suining Branch, 629000, Sichuan, China） Abstract：In this paper , cyclic voltammetry curves (CV) and chronoamperometry(CA) in conjunction with the Scharifker-Hills Model (SH) were used to research the initial stage of Ni-W alloy electro-deposition in acidic sulphate electrolyte. The results indicated that the electro-deposition of the Ni-W alloy onto glassy carbon electrode consisted of nucleation and growth, the crystal nucleation of plating improved as the concentration of WO42- increased and its reduction intermediate products could be considered as favorable sites of the Ni-W alloy. According to the analysis of Scharifker and Hills model, the pure Ni without W nucleation process follows three dimension-instantaneous mechanism, while the Ni-W alloy is progressive nucleation mechanism at a lower overpotential, which slightly deviated from progressive nucleation to be instantaneous nucleation mechanism at higher overpotential. Keywords: nickel–tungsten alloy; electro-deposition; cyclic voltammetry curves; chronoamperometry；Scharifker and Hills model 0引言 镀铬层由于表面美观、机械性能优良、具有很高的硬度和耐磨性，在过去10多年的时间里为防护装饰性镀层和功能性耐磨损镀层得到了广泛的应用。但是镀铬工艺存在很多缺点：电流效率极低，仅8%16%，造成能量损耗；分散能力和覆盖能力差，需要使用象形阳极和辅助阴极；最致命的缺点是镀液呈强酸性，强氧化性，腐蚀性极强，毒性很大，排出的废水、废气严重污染环境，对人体健康造成很大的危害。镀铬过程中产生的六价铬是一种危险的致癌物。世界各国的环保部门对铬雾和含铬废水的排放都进行了严格的控制。因此，镀铬工艺已经面临被淘汰的命运，寻找一种新型的代铬镀层成为金属和电沉积领域迫切需要解决的难题。 钨也