高速钢磨削再生过程中有价金属钨及杂质P的变化行为.docVIP

毕业论文 高速钢磨屑再生过程中 有价金属钨及杂质磷的变化行为探讨  摘 要 钨是我国在世界上具有优势地位的稀缺资源。我国的有色金属储量不均，贫矿多富矿少。同时，我国对废钨资源的利用也很低，如果我国的废钨的利用率能提高10%，每年就可以少消耗我国1.4万吨钨储量。众所周知，高速钢磨屑中含有大量的钨，具有很高的回收利用价值，所以对高速钢磨屑中废钨的利用应予重视。 论文在热力学分析的基础上，经过对国内外高速钢磨屑回收技术的分析比较后，采用硅热法回收高速钢磨屑中的有价金属钨。通过采用冶金强化的方法回收高速钢磨屑中的有价金属钨，初步探索不同条件下高速钢磨屑中钨及杂质磷的变化行为规律。论文对高速钢磨屑进行磁选除杂与不磁选除杂对比，探讨硅的加入量、石灰用量、萤石用量、单位炉料热效应等条件参数变化因素对钨的回收率及杂质磷的变化影响，确定回收有价金属钨的最佳条件。 通过试验研究表明：采用硅热法工艺回收高速钢磨屑中的钨是可行的，钨的回收率在80％以上。同时，试验还表明高速钢磨屑中铬的回收率大于45％，钼的回收率不低于85％。，回收工艺具有明显的经济效益和社会效益，是一种可行的回收高速钢磨屑中有价金属钨的方法。 关键词：高速钢 磨屑　再生利用 变化行为   ABSTRACT The tungsten is an our country be having the advantage position in the world , and it’s a rare resources. The non-ferrous metallurgry’s reserves of our country is odds. Poor mine is more, and rich mine is lack. At the same time, the use of the depose tungsten in our country also quite low. If the use of the depose tungsten improve 10%, it will reduce 1.4 ten thousands tungsten mine of our country. The high-speed steel bits have a mass of tungsten, so it has very supermal reclaim using value. So that we must regard the depose tungsten of the high-speed steel. On the basis of thermodynamic analysis，the discourse course by comparing reclaim technique of inside and outside country, plan get across Silicon—thermal process for recovering W metal in the form of secondary alloy from scale of high—speed steel. Search after the W and P’s ransformation conducts of High—speed steel on the different conducts. The effects of lime，reducing reagent and unit therm al on metal recoveries were analyzed. Make sure the best condition for reclaiming Secondary alloy form high—speed steel. The results show that the technical is practicable. The recover ratio of W is more than 80 percent，the ratio of Cr is over 45 percent，the ratio of V is about 85 percent．The quality of product is stable and the product can meet the need of steelmaking．The waste of to grinding dust is full of used and remarkable social —eco