9_phase【DOC精选】.docVIP

phase/AL91P2_3b 3. (b) A liquid is added as a solvent forming an ideal solution. Comment on the vapour pressure of the solution as compared with that of the pure solvent. The vapour pressures of pure methanol and ethanol at 25oC are 89.2 mm Hg and 44.6 mm Hg respectively. A mixture containing 32.0 g of methanol and 184.0 g of ethanol behaves as an ideal solution. Calculate the partial vapour pressure of each component, the total vapour pressure of the mixture and the composition of the vapour. (Relative atomic masses : H, 1.9; C, 12.0; O, 16.0) (7 marks) phase/AL92P1_2f 2. (f) The vapour pressure versus mole fraction diagram for a two component system (A and B) is shown below: State the reason(s) which give(s) rise to the shapes of the curves in the diagram. What do points P and Q represent? What assumption(s) would have to be met for the curves to be linear? Give an equation to represent this behaviour. (4 marks) phase/AL92P1_2g 2. (g) For the phase diagram below: Identify the points X and Y. Which two points in the diagram define the sublimation curve? Mark on the diagram, using the symbol B, the normal boiling point. Suggest the meaning of the curve YW. (4 marks) phase/AL92P2_2c 2. (c) (i) The distribution coefficient of a compound X between two immiscible liquids D and E is 12. X is more soluble in D. What mass of X can be attracted from 50 cm3 of a solution of E which initially contains 4 g of X when shaken with 100 cm3 of D? (ii) The total vapour pressure exhibited by a mixture of immiscible liquids is equal to the sum of their individual saturated vapour pressures. Explain why steam distillation enables some heat-sensitive organic compounds to be distilled at a lower temperature than their normal boiling points. A mixture of two