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制冷剂与载冷剂专用课件
Chapter 2Refrigerant Second Coolant Objectives 1. Understand requirements for refrigerants on thermodynamics, physics chemistry, safety and environment. 2. Be familiar with the characteristics and applications of R717 and R22. 3. Identify the types, properties and applications of second coolants. 2.1 Refrigerant Function:The working medium in a refrigeration system is called refrigerant, like “blood” for our body. circulate flow-thermodynamic properties will be changed -exchange energy with environment condense-heat rejection phase change evaporate-heat extraction 2.1 Refrigerant Development history Aether, low temperature PeB, easily explode when air leaks inward. 1866,Windhausen, CO2, high pressure (Pc=8 MPa). 1870,Carl Linde,NH3, large refrigeration systems. 1874,Raul Picte, SO2, intense toxicity, phased out gradually. 1929-1930,Thomes Midgley, R12, the earliest to be used. 1974, some freon was found to destroy ozone layer. 1980’, It is determined that CFC is the substance to worsen green house effect and destroy ozone layer. 2.1 Refrigerant 2.1.1 requirements for refrigerant 1. Environmental friendly Lower greenhouse effect and depletion of ozone layer 2.1 Refrigerant 2. thermodynamic properties (1) appropriate pressure Condensing pressure Pc ? Pc ??12~15 bar Evaporating pressure Pe Pe ? B (atmospheric pressure) appropriate Pc / Pe , for one-stage compression system, Pc / Pe ??8~10 1. Thermodynamic properties (2) Appropriate qv Refrigeration system, Q0=qmq0=qVqv Large device: Higher the q0 and qv , smaller the qm and qV,and smaller the compressor size Small device: Larger qv is desired. 1. Thermodynamic properties (3) Higher critical temperature and lower freezing temperature (4) smaller k (The discharge temperature t2 should not be excessive.) For isentropic compression, higher t2 would
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