奈米材料-介观化学世界.PDFVIP

(New States) (Nanochemistry) (Surface Energy) (Quantum Confinement Effect) (Nano-microstracture) 60 1~100 nm 100 nm 1nm Length 1~20 Debye (1-3) (4-6) (Ouautung Flucctuation) Nature States) Corral)(7) Quantum Corral (New (Quantum 61 (STM) 48 / Quantum Corral (edge wave) Energy 2Molecules Cluster Lumo5 Q-Size Particle Semiconductor Conduction Band (L) Cmo Bandgap Bandgap Homo5 Valence Band (VB) (CB) 62 Dimension Length (Ouantum Confinement) (Bandgap) (8) InAs CdS CdSe InP (Nanocrystal) TiO2(9- 12) Normalized fluorescence % of Atoms in Bulk/on Surface (a) 6.0 4.6 3.6 2.8 InAs (b) 4.6 3.5 3.0 4.6