郑州大学有机化学第二章烷烃题稿.pptVIP

Configuration (构型): the CH3 radical is planar (sp2 hybridized carbon) 6.3 Autoxidation (自动氧化) R-H Reactivity (活性): 3o 2o 1o The O–O bond of an alkyl hydroperoxide is quite weak, and it can break and produce radicals that can initiate other chains: RO–OH RO? + ?OH Benzoyl Peroxide (过氧化苯甲酰) Benzoyl peroxide is an organic compound in the peroxide family. It consists of two benzoyl groups bridged by a peroxide link. The oxygen-oxygen bond in peroxides is weak. Thus benzoyl peroxide readily undergoes homolysis, forming free radicals: (C6H5CO