Chemometrics.ppt

Paul Geladi feb 06 Is Hyperspectral Imaging an Analytical Instrument? Paul Geladi Content Short introduction of the topic Space imaging Instrumentation Examples, history and philososphical thoughts Airborne hyperspectral imaging /getstart/hyprspec.htm Randall Smith 2001 Some airborne systems Conclusions Airborne Not too much chemometrics Calibration / standardization / correction problems Comparison of airborne / ground spectra Lab versus airplane We have our own “sun” It is controllable Only within limits Problems still exist How to quantify / correct problems? Content Short introduction of the topic Space imaging Instrumentation Examples, history and philososphical thoughts AVIRIS Rotating filter wheel Prism-Grating -Prism Interferometer Content Short introduction of the topic Examples, history and philososphical thoughts Standardization Calibration Sampling problems Comparison Content Short introduction of the topic Examples, history and philososphical thoughts Standardization Calibration Sampling problems Comparison Reference values (y) Pure standards Known mixtures Wet chemistry Reference values Impossible to measure wet chemistry in every pixel All standards are heterogeneous at high magnification Not always possible with synthetic standards Content Short introduction of the topic Space imaging Instrumentation Examples, history and philososphical thoughts Standardization Calibration Sampling problems Comparison Content Short introduction of the topic Examples, history and philososphical thoughts Standardization Calibration Sampling problems Comparison Examples (removed, paper in review) Comparison with a spectrometer Integration over a volume / area Only 1 detector High resolution 216 Wide l range possible Lower noise Information in pixels / depth? Many detectors Low resolution 212 Limited l range Noisier Comparison Linearity better controlled No populations Quick Linear? Missing pixels Populations! Slow