CO+等气体在苯酚中的溶解度的测定及关联.pdf

A049 1 CO ?1 2 1 430074; 2 211 300072 RK CO CO2 N2 O2 CO CO2 CO N2 O2 The measurement and correlation of carbon monoxide and other gases solubility in phenol ZHANG Guangxu 1 2 ,WU Yuanxin11, MA Peisheng 2,WU Guangwen1 2 and LI Dinghuo1 (1Department of chemical Engineering ,Wuhuan Institute of Chemical Engineering Technology, Wuhan 430074, hubei, China ; 2 School of Chemical Engineering , Tianjin University ,Tianjin 200073,China ) Abstract The new instrument of measuring gas solubility was designed, and the solubility of carbon monoxide, oxygen and other gases in phenol were measured respectively under the temperature in range of 55 to 95 and gas pressure in range of 1.0 to 8.00MPa, the results showed that solubility of carbon dioxide were decreased with temperature increasing, but others were increasing; By using the regular-solution theory and the virial expansion for the Redlich-Kwong equation of state, an equation was proposed to relate the solubility of the gases in the non-volatile solvent to temperature and pressure. The results revealed the equations used to correlate high-pressure gas solubility of oxygen and carbon monoxide and other gas in phenol at various temperatures were accurate. Keywords measuring gas solubility, phenol, carbon monoxide ? 1964 :(0271 CO O2 N2 O2 DPC CO O2 CO O2 DPC RK 1 1.1 CO CO2 1 1 Fig. 1 Schematic diagram of experimental setup for gas solubility 2 1.2 1 2 3 4 5 6 7 8 1.3 CO2 1.3 21 CO CO2 2 2 CO 2.1 1.2 CO27 CO2 CO 25 3 304 K 313 K 1 s 1 CO2 Table1 The comparison of the experimental data and literature data about the solubilities of carbon dioxide in water T=304K T=313 K P/ MPa 1.013 2.026 3.039 4.558 s 0.00560 0.00952 0.01332 0.0179 P/ MPa 1.01 2.03 3.04 4.56 s 0.00626 0.00959 0.01329 0.0180 P / MPa 1.013 2.026 3.039 4.558 s 0.00460 0.00843 0.01167 0.01572 P / MPa 1.07 2.03 3.04 4.59 S 0.00496 0.00846 0.01117 0.01559 2 CO Table2 The comparison of the experimental data and theoretical data about the solubilities of carb