Catalytic diesel particulate filters with highly dispersed ceria Effect of the soot-catalyst contact on the regeneration performance.pdfVIP

Catalytic diesel particulate filters with highly dispersed ceria Effect of the soot-catalyst contact on the regeneration performance.pdf

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Catalytic diesel particulate filters with highly dispersed ceria Effect of the soot-catalyst contact on the regeneration performance.pdf

Applied Catalysis B: Environmental 197 (2016) 116–124 Contents lists available at ScienceDirect Applied Catalysis B: Environmental journal homepage: /locate/apcatb Catalytic diesel particulate ?lters with highly dispersed ceria: Effect of the soot-catalyst contact on the regeneration performance Valeria Di Sarli a,?, Gianluca Landi a, Luciana Lisi a, Anna Saliva b, Almerinda Di Benedetto b a Istituto di Ricerche sulla Combustione, Consiglio Nazionale delle Ricerche (CNR), Piazzale V. Tecchio 80, 80125 Napoli, Italy b Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Università degli Studi di Napoli Federico II, Piazzale V. Tecchio 80, 80125 Napoli, Italy article info Article history: Received 14 October 2015 Received in revised form 24 January 2016 Accepted 31 January 2016 Available online 3 February 2016 Keywords: Catalytic diesel particulate ?lters Soot Catalyst dispersion Soot-catalyst contact Ceria abstract In this work, the effect of the soot-catalyst contact on the regeneration performance of a diesel particulate ?lter (DPF) wash-coated with nano-metric ceria particles was investigated. The catalyst load was suitably chosen to avoid major changes in pore size distribution of the original ?lter. Different amounts of soot were loaded into the ?lter, thus varying the catalyst/soot ratio. Filter samples were characterized by N2 physisorption at 77 K, Hg intrusion porosimetry and SEM/EDX analysis. Regeneration tests were performed in a lab-scale plant by temperature programmed combustion of soot. At the lowest soot load explored (corresponding to catalyst/soot ratio ~100 w/w), the soot particles deeply penetrate into the macro-pores of the ?lter walls coming in close touch with highly dispersed ceria. At the highest soot load explored (catalyst/soot ratio ~20 w/w), in addition to the soot particles trapped inside the macro-pores, a thick soot cake layer accumulates on top of the catalytic walls of the ?lter. The former condition resu

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