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Filamentary superhydrophobic Teflon surfaces Moderate apparent contact angle but superior air-retaining properties.pdf

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Filamentary superhydrophobic Teflon surfaces Moderate apparent contact angle but superior air-retaining properties.pdf

Journal of Colloid and Interface Science 482 (2016) 175–182 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: /locate/jcis Regular Article Filamentary superhydrophobic Te?on surfaces: Moderate apparent contact angle but superior air-retaining properties Rosa Di Mundo a,?, Francesco Bottiglione a, Fabio Palumbo b, Michele Notarnicola c, Giuseppe Carbone a,d a Department of Mechanics, Mathematics and Management, Politecnico di Bari, v.le Japigia 182, 70126 Bari, Italy b CNR-NANOTEC, via Orabona 4, 70126 Bari, Italy c Department of Civil and Environmental Engineering and Chemistry, Politecnico di Bari, via Orabona 4, 70126 Bari, Italy d CNR – Institute for Photonics and Nanotechnologies U.O.S. Bari, Department of Physics ‘‘M. Merlin”, via Amendola 173, I-70126 Bari, Italy graphical abstract article info Article history: Received 25 June 2016 Revised 27 July 2016 Accepted 27 July 2016 Available online 28 July 2016 Keywords: Te?on Polytetra?uoroethylene Superhydrophobicity Air retaining surface Dynamic contact angle Drop impact Contact time Underwater surface abstract Hypothesis: Micro-scale textured Te?on surfaces, resulting from plasma etching modi?cation, show extremely high water contact angle values and fairly good resistance to water penetration when hit by water drops at medium-high speed. This behavior is more pronounced when these surfaces present denser and smaller micrometric reliefs. Tailoring the top of these reliefs with a structure which further stabilizes the air may further increase resistance to wetting (water penetration) under static and dynamic conditions. Experiments: Conditions of the oxygen fed plasma were tuned in order to explore the possibility of obtaining differently topped structures on the surface of the polymer. Scanning Electron Microscopy (SEM) was used to explore topography and X-ray Photoelectron Spectroscopy (XPS) to assess chemical similarity of the modi?ed surfaces. Beside the usual