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Tribo-chemical behavior of eutectoid steel during rolling contact friction.pdf
Applied Surface Science 388 (2016) 40–48
Contents lists available at ScienceDirect
Applied Surface Science
journal homepage: /locate/apsusc
Tribo-chemical behavior of eutectoid steel during rolling contact friction
Y. Zhou a, Z.B. Cai a, J.F. Peng b, B.B. Cao a, X.S. Jin b, M.H. Zhu a,b,?
a Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, China b Tribology Research Institute, State Key Laboratory of Traction Power, Southwest Jiaotong University, Chengdu 610031, China
article info
Article history: Received 14 October 2015 Received in revised form 27 April 2016 Accepted 27 April 2016 Available online 30 April 2016
Keywords: XPS Tribo-chemical Rolling contact friction Eutectoid steel Tribo-?lm
abstract
The tribo-chemical behavior of the eutectoid steel during rolling contact friction is investigated via scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and electron probe X-ray microanalysis. The worn surface is divided into three zones: matrix zone (without friction), tribo?lm zone (formed during friction) and delamination zone (tribo-?lm spalling). The different chemical states of atoms between those three zones and the air were investigated using the XPS analysis. The results showed that the matrix zone is composed of Fe2O3, FeO and metallic Fe, while the tribo-?lm and delamination zones only contain Fe2O3 and FeO. Where the tribo-?lm is formed, the absorptive ability of O and C atoms on the top 2–3 atomic layers is probably weakened, while the exposed fresh metal in the delamination zone tends to be continuously oxidized and form tribo-?lm. The tribo-chemical reaction in the delamination zone is more activated than that in the other two zones. The protective nature of the tribo-?lm probably maintains a low friction coef?cient under rolling contact friction condition.
? 2016 Elsevier B.V. All rights reserved.
1. Introduction
Eutectoid steel has been widely
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