新型铜基催化剂的制备及其在湿式催化氧化中的催化性能.pdf

D056 新型铜基催化剂的制备及其在湿式催化氧化中 的催化性能 张立红 李峰 D.G.Evans 段雪* （北京化工大学可控化学反应科学与技术基础教育部重点实验室, 北京 100029） 要 本文采用传统的共沉淀法制备了铜锌铝、铜锌铁铝及铜锌锰铁铝系列的碳酸根型层状双 羟基氢氧化物，通过 X 射线衍射(XRD) 、红外光谱(FT-IR)、热重及微商热重分析(TG-DTG) 、低 温氮气吸－脱附实验及X 光电子能谱(XPS)等研究手段对LDHs 及其在773 K 的焙烧 物的晶相 组成、结构和表面化学状态进行了分析。结果表明在焙烧 物中均存在一定形式相互作用的复合 金属氧化物，层状前体的结构特征决定了其焙烧 物的物化性能。另外，通过对LDHs 焙烧 物 的苯酚催化氧化性能研究发现，含铜锌铁铝氧化物催化剂具有较强的催化活性，这与其表面催化 活性中心Cu2+离子的化学状态和分布状态密切相关。 关键词 复合氧化物 层状双羟基化合物 苯酚氧化 催化作用 Preparation and Activity of Novel Cu-based Catalyst for the Catalytic Wet Oxidation ZHANG Lihong, LI Feng, David G. Evans and DUAN Xue* (Education Ministry Key Laboratory of Science and Technology of Controllable Chemical Reactions, Beijing University of Chemical Technology, Beijing 100029, P. R. China) Abstract In this paper, we report the synthesis of layered double hydroxides (LDHs) containing 2+ 2+ 2+ 3+ 3+ Cu , Zn , Mn , Fe and Al cations were synthesized by the coprecipitation method. The physicochemical properties of both the synthesized LDHs and its calcined product at 773 K/3h were investigated by various analytical and spectroscopic methods such as powder X-ray diffraction (XRD), FT-IR spectroscopy, chemical analysis, N2 adsorption-desorption experiments, and thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS). These techniques allowed us to confirm that the calcined LDHs-layered double oxides (CLDHs) samples contained a composite oxide. At room temperature and atmospheric pressure, oxidation of aqueous phenol solutions by hydrogen peroxide in the presence of the calcined LDHs was carried out. The results show that the CuZnFeAl-CLDH has the highest catalytic activity for conversion of phenol,