溶胶凝胶法制备Y2SiO5Ce3+,Yb3+.docVIP

题 目： Y2SiO5：Ce3+，Yb3+  毕业设计（论文）任务书 毕业设计（论文）题目：溶胶-凝胶法制备：Y2SiO5：Ce 3+, Yb3+ 荧光粉及发光性能研究 毕业设计（论文）内容： 1.确定激活剂的最佳浓度。2.确定荧光粉的最佳制备条件。3.考察Ce 3+, Yb3+掺杂的Y2SiO5荧光粉的发光性能 毕业设计（论文）专题部分： 研究溶胶凝胶法制备：Y2SiO5：Ce 3+, Yb3+荧光粉的方法，并应用到新型太阳能电池，提高太阳能电池的光电转换效率。  摘要 随着科学技术的发展和人们环境保护意识的提高，太阳能电池的应用越来越受到人们的关注。其中，太阳能电池的光电转化效率制约着太阳能电池的应用。由于硅太阳能电池占据着太阳能电池市场的主导地位，而稀土Yb3+离子的发光刚好与硅禁带宽度匹配，因此Yb3+掺杂的发光材料非常适合做提高硅太阳能电池的红外下转换材料研究。 本论文采用溶胶凝胶法合成Ce 3+, Yb3+掺杂的Y2SiO5荧光粉，通过荧光光谱分析，考察掺杂浓度，晶化温度对荧光粉发光性能的影响，确定合适的工艺条件。合成掺杂不同浓度Ce3+的Y2SiO5荧光粉，Ce3+的掺入浓度分别为1、2、3、4mol%，晶化时间为3h,观察在356nm激发下测得的发射峰，在444nm监测下测得的激发峰，确定最佳掺杂浓度。选择晶化温度为900℃，1000℃，1100℃，1200℃，晶化时间为3h。观察在356nm激发下测得的发射峰，在444nm监测下测得的激发峰，确定最佳晶化时间。掺杂Ce 3+ 浓度为2%，掺杂不同浓度的Yb3+的掺杂浓度为9mol%，在1200℃下晶化3h合成Y2SiO5：Ce 3+, Yb3+的发光性能最好。 关键词：荧光粉，溶胶凝胶法，发光性能 Abstract With the development of science and technology，and peoples environmental awareness, application of solar cells more and more peoples attention. Among them, the photoelectric conversion efficiency of solar cells restricts the application of solar cells. As the silicon solar cell solar cells occupy a dominant market position, Yb3 + ions of rare earth luminescence coincides with the band gap of silicon match, so Yb3 +-doped light-emitting material is very suitable for improving silicon solar cell infrared conversion materials under study. The paper by sol-gel synthesis Ce3+, Yb3+ doped Y2SiO5 phosphor by fluorescence spectroscopy to study the doping concentration, crystallization temperature of the phosphors performance, determine the appropriate process conditions. Synthesis of different concentrations of Ce3+ doped phosphor Y2SiO5, Ce3+ incorporation concentrations were 1,2,3,4 mol%, the crystallization time of 3h, observed in the measured excitation 356nm emission peak at 444nm was measured to monitor excitation peak, determine the best concentration of doping. Select the crystallization temperature of 900℃, 1000℃, 1100℃, 1200℃, the crystallization time of 3h. Observations measured at 356nm excitati