阳极H2S杂质气体对PEMFC性能影响的研究.pdfVIP

??28??????? 2006???? ?人????????? JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY V01??28 Suppl???? NOV??2006 ???H2S?????????PEMFC?????????о? ????1,2?±???1???? (I???й?????????????????о??????????????? ??1????????1???????1 ????116023??2???й??????о??????????100039) ?????о????????(H2)?е?H2S??????????????(PEMFC)????????????????S????????? ???????????????HzS????????????????????????????????????????????????????????????? ????????????????????????????ж?????????????????????????(cv)???????????????????? ??CV?о????H2s???????????Pt????????棬????????λ?????????????????????????-503??s????? ???绯??迹(EIS)??????????H2+50 ppm}?S??Hz????????μ??迹????????????????s????????? ????????????????????????????绯?????????????????迹????? ??????HzS??PEMFC????????? ?绯??迹 ?????????TM 911??48 ????????A ???±???1671??4431(2006)???11??04??54-08 Effect of Hydrogen Sulfide in Fuel Stream on PEMFC Performance SHIWei??yal???YIBao??-lianl??HOUMin91??JINGFen??nin91??MINGPing-wenl (1 Fuel Cell RD Center??Dalian Institute of Chemical Phyi???Chinese Academy of Sciences??Dalian 116023??China?? 2??GraduateUniversity ofthechineseAcademyofScienees??Beijin9100039??China) Abstract??A study of H2S in fuel steam poisoning of membrane dectrode assemblies(MEAs)with Pt catalyst in pmton exchange membrane fud ceils(PEMFC)is presented??The severity of H2S poisoning varies depending 011 the concentra- tioa??current dertsity and cell operating temperature??but considerable cdl performance deterioration is inevitable because the poisoning effect due tO H2S b eumu|adve??No recovery is observed after exposLtre to neat H2??however??complete re- coveryofthe ceO performancejobtained by several cycle voltammetry scans between 0??1??4V vs DHE??Effect ofHzS On the anode j studied in an H2?half cell with electrochemical impedance spectrooeopy??and the experimental results in?? dieate charge-transfer resistance increase due??H2S poisoning?? Key words??hydrogen sulfide,PEMFC?? cyclic voltammetry?? electrochemical impedance spectroscopy ?????????????(Proton