5ConductivePolymer2研讨.ppt

* Two conditions to become conductive: There are two types of doping: Oxidation with halogen（卤素，如I2） (called p-doping or 氧化掺杂). [CH]n + 3x/2 I2 —— [CH]nx+ + x I3- Reduction with alkali metal (碱金属，如Na） (called n-doping or 还原掺杂). [CH]n + x Na —— [CH]nx- + x Na+ * Doping process The halogen doping transforms polyacetylene to a good conductor. Oxidation with iodine causes the electrons to be jerked out（拉出） of the polymer, leaving “holes” in the form of positive charges（阳离子） that can move along the chain. * The iodine molecule attracts an electron from the