鈷掺杂二氧化钛纳米管的制备及光催化能研究毕业专业论文.docxVIP

钴掺杂二氧化钛纳米管的制备及光催化性能研究摘要随着人类生活的进步，环境污染问题也日益严重，TiO2光催化技术在环保、化工、医药、食品等领域都发挥重要的作用。本论文研究的主要内容是：一、利用共沉淀法和水热煅烧法制备出TiO2纳米管，通过单因素实验和正交试验研究水热反应温度、水热反应时间、煅烧温度、煅烧时间对TiO2光催化率的影响，从而确定最佳工艺参数。二、利用前面所得到的最佳反应条件制备金属钴离子掺杂量不同的二氧化钛，对所得到的样品通过X射线衍射（XRD）和透射电镜（TEM）分析样品的晶体结构和形貌，通过EDS对样品进行形貌分析。以亚甲基蓝作为目标降解物研究不同钴离子掺杂量的样品光催化率趋势，从而得到钴离子最佳掺杂量，使该样品对亚甲基蓝的降解率最高。实验结果表明：当水热反应温度、水热反应时间、煅烧温度、煅烧时间分别为 时，所得到的TiO2催化率最高，为 ；当钴离子掺杂量为0.5%和1.3%时，所得到的Co-TiO2催化率最高，为97.2%。XRD结果表明最佳工艺参数下制备出的钛氧化物为锐钛矿相。TEM结果表明，最佳工艺参数下制备出的钛氧化物为纳米管结构，管长为30-70 nm,管径为15nm左右。EDS分析表明钴离子掺杂在二氧化钛晶格中。关键词：钴掺杂、二氧化钛、亚甲基蓝、光催化率Preparation and Photocatalytic Performance Research of Co-doped TiO2 nanotubesABSTRACTWith the progress of people‘s lives, environmental pollution has become increasingly severe.TiO2 photocatalytic technology have played an important role in the environment, chemical industry, medicine, food and other fields. The main contents of this essay are:1.First of all,prepare the TiO2 nanotubesby co-precipitation method and hydrothermal calcination.Then, determine the best process parameters with the method ofstudying the hydrothermal temperature, the hydrothermal reaction time, the calcination temperature and the impacts of calcination time on the TiO2 photocatalytic rate by single factor experiment and orthogonal experiment.2.Firstly,take advantage of the best process parameters previously received to prepare the titanium dioxide with different mixed amounts of cobalt metal ion, and then analyze the crystal structure and morphology of the sample by X-ray diffraction (XRD) and transmission electron microscopy (TEM), as well as analyze the morphology of the sample by EDS. Finally, use the methylene blue as target degradation to study photocatalytic rate trend of the samples with different mixed amounts of cobalt ion, so that receive the best mixed amount of cobalt ion, which can make the degradation rate of methylene blue by the sample is highest.The results show that: when the hydrothermal reaction temperature, hydrothermal reaction t