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材料物理导论作业样板(刘教授)
Homework one(2012-4-27)
1. The number of vacancies(空缺) in some hypothetical(假设的、假定的) metal increases by a factor of 5 when the temperature is increased from 1070 K to 1180 K. Calculate the energy for vacancy formation (in J/mol)(空位形成能) assuming that the density (密度)of the metal remains the same over this temperature range.
Solution:
As we know n=Nexp(-Qv/RT),
where the Qv is the energy for vacancy formation
So n1/n2 =exp(Qv)exp(1/T1 -1/T2) ,
n1/n2 =5, T1=1070K,T2=1180K
the key Qv=1.60935 Kj/mol
2. A Frenkel defect (弗伦克is composed with which of the following?
A. A cation interstitial and a cation vacancy
B. A cation interstitial and an anion interstitial
C. A cation vacancy and an anion vacancy
D. An anion interstitial and an anion vacancy
KEY:A
3. For an alloy (合金)that consists of 37.7 wt% Pb and 62.3 wt% Sn, what is the composition (组分)(a) of Pb (in at%), and (b) of Sn (in at%)? The atomic weights(相对原子质量) for Pb and Sn are 207.2 and 118.7 g/mol, respectively(分别地).
Solution
Assuming that the mass of alloy is 100g, thus, the mass of Pb is 37.7g; the mass of Sn is 62.3g. So the quantity of the two materials can be calculated as follows:
So the composition of Pb (in at%) and of Sn (in at%)can be calculated as follows:
4. Impurity atoms(杂质原子) in ceramic(陶瓷) materials may form substitutional (置换)and interstitial(间隙) solid solutions.
A. True B. False
KEY:A
5. What are the two fundamental types(基本类型) of dislocations(位错)?
KEY:Edge dislocation、Screw dislocation
6. Two metal specimens(金属式样), A and B, have ASTM grain(细粒) size numbers of 3 and 8, respectively(分别地). Which specimen has the larger grain size?
A.
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