硅烷在涂料中的应用silanesforcoatings选编.pptVIP

Silanes for Coatings硅烷在涂料中的应用 Shiu-Chin Cindy Su 蘇黃秀琴 Momentive Performance Materials Shiu-Chin.Su@ 914-784-4905 Company History 公司的历史 1993 Divestiture 2000 Name Change 2003 Acquisition Late 1950’s 2006 Divestiture Function of Silanes in Coatings硅烷在涂料中的特殊功能 Adhesion Promotion 增强附着力 Especially between organic polymers and inorganic oxide substrates 特别是在有机聚合物与无机氧化物之间 Some examples exist for adhesion to nonfunctional organic substrates 在难附着的有机底材上增强附着力 Crosslinking 交联剂 Convert reactive polymers (isocyanate, polyol, polyamine) to moisture cure chemistry 可反应性聚合物＝》具有潮气固化反应的特点 VOC Reduction 减少 VOC Dispersion 帮助分散 Compatibilize high-energy particulates with organic matrices 帮助高能量粒子在有机物中的分散； Silanes are Dual-Functional Molecules硅烷是双功能的分子 Organic portion bonds or interacts with a polymer or organic surface. 有机基团－可以与聚合物或有机表面形成化学键； Silane portion bonds or interacts with metal, glass or inorganic surface (adhesion). 硅烷基团－可以与金属，玻璃等无机表面形成化学键； Can react with other silane-modified polymers (crosslinking). 可与其它硅烷改性的聚合物反应（交联） Hydrolysis and Condensation水解和缩合反应 1. Hydrolysis Reaction 水解反应 OH H 2 N(CH 2 ) 3 Si (OCH 3 ) 3 H 2 N(CH 2 ) 3 Si OH + 3 CH 3 OH ( Silquest A-1110 silane ) OH 2. Condensation 缩合反应 OH OH H 2 N(CH 2 ) 3 Si OH + HO Si H 2 N(CH 2 ) 3 Si O Si OH OH H 2 O - H 2 O Surface silanol Functionalized surface Hydrolysis and Condensation of Organofunctional Silanes  pH值对硅烷水解和缩合反应的影响 log k pH 水解 (kobs, s-1) 缩合 (kobs, M-1s-1) E. R. Pohl et. al. Function of Silanes in Coatings硅烷在涂料中的特殊功能 Adhesion Promotion 增强附着力 Especially between organic polymers and inorganic oxide substrates 特别是在有机聚合物与无机氧化物之间 Some examples exist for adhesion to nonfunctional organic substrates 在难附着的有机底材上增强附着力 Crosslinking 交联剂 Convert reactive polymers (isocyanate, polyol, polyamine) to moisture cure chemistry 可反应性聚合物＝》具有潮气固化反应的特点 VOC Reduction 减少 VOC Dispersion