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Low-temperature CO oxidation on Aufumed SiO2-based catalysts prepared from Au(en)2Cl3 precursor.pdf

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Low-temperature CO oxidation on Aufumed SiO2-based catalysts prepared from Au(en)2Cl3 precursor

/locate/apcata Applied Catalysis A: General 326 (2007) 89–99Low-temperature CO oxidation on Au/fumed SiO2-based catalysts prepared from Au(en)2Cl3 precursor Haoguo Zhu, Zhen Ma, Jason C. Clark, Zhengwei Pan, Steven H. Overbury, Sheng Dai * Center for Nanophase Materials Sciences, and Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA Received 16 February 2007; received in revised form 19 March 2007; accepted 1 April 2007 Available online 12 April 2007AbstractMany gold catalysts have been actively surveyed, but Au/SiO2 catalysts that are highly active for CO oxidation still remain evasive. In this work, gold nanoparticles well dispersed on Cab-O-Sil fumed SiO2 were prepared using Au(en)2Cl3 (en = ethylenediamine) as the precursor, and found to be very active for CO oxidation below 0 8C. The catalyst pretreatment via reduction and calcination, effect of gold loading, post-treatment in acidic and basic media, catalyst deactivation, storage, regeneration, and effect of surface modification by other metal oxides were explored. The results provide new perspective on the activation and promotion of active Au/SiO2-based catalysts. # 2007 Elsevier B.V. All rights reserved. Keywords: Gold catalysis; Nanoparticles; CO oxidation; Silica; Au(en)2Cl31. Introduction Since Haruta and coworkers demonstrated that supported gold nanoparticles could be highly active for low-temperature CO oxidation [1], many different gold catalyst formulations have been reported. Deposition-precipitation, coprecipitation, and impregnation are common synthetic approaches utilized to prepare gold catalysts on a variety of supports including TiO2, Al2O3, Fe2O3, and CeO2 [2–6]. Among the various combina- tions of supports and synthetic methods utilized, the deposition- precipitation of Au(OH)xCl4x complexes onto TiO2 leads to highly active Au/TiO2 that is the most studied gold catalyst in the literature [2–6]. However, despite the wide use of SiO2 as a support for a var