水溶聚丙烯酸穩泡剂的研制实验论文.docxVIP

创新实践培训论文题目：水溶性聚丙烯酸稳泡剂的研制学院：材料科学与工程学院专业名称：高分子材料与工程姓名：徐小剑 姓名：闫调姓名：陈强 指导教师：孟江燕二〇一三年七月水溶性聚丙烯酸稳泡剂的研制徐小剑，闫调过，陈强（南昌航空大学材料科学与工程学院南昌 330063）摘要：水溶性聚合物在采矿、采油、油漆制造、污水处理等业领域中都有十分广泛的应用。聚丙烯酸水溶液在不同温度下都有着很高的粘度,采用在发泡体系中溶液聚合法直接增加发泡体系的泡沫稳定性，从而提高高温下的泡沫稳定性。在实验室环境下采用气流来评价法泡沫的稳定性，通过实验筛选水溶性聚合物稳泡剂，最后通过合成聚丙烯酸作为高温体系下的稳泡剂。详细测量了温度与泡沫衰变时间的关系，记录了泡沫衰变时间与泡沫体积的相关数据。通过涂料黏度计测量了一部分发泡体系的粘度。实验结果表明75℃高温时，用PEG2000作为交联剂，聚丙烯酸稳泡剂浓度为1:8时，稳泡性能较好。分析发泡液温度与半衰期的关系，发现其满足指数关系。对泡沫衰变时间与泡沫体积的数据进行拟合，发现泡沫衰变反应成指数规律变化。通过讨论稳泡剂的浓度对粘度的影响，在一定范围内发泡液的粘度越大，泡沫的稳定性也越好。关键词：聚合物稳泡剂半衰期泡沫衰变曲线聚丙烯酸指导老师签名：Preparation for polyacrylic acid foam stabilizerXuXiaojian，Yan Tiaoguo，Chen Qiang（Nanchang Hangkong University ,Nanchang,330063)Abstract:The soluble polymers in the mining, oil, paint manufacturing, sewage treatment and other industries have a very wide field of application. At different temperatures polyacrylic acid solutionhave a very high viscosity of the foaming system using ansolution polymerization method to directly increase the foam stability of foaming system, thereby improving the foam stability at high temperatures.Airflow in a laboratory environment to evaluate the method using foam stability, soluble polymer by experiments screening foam stabilizer, and finally through the synthesis of polyacrylic acid as a high temperature foam stabilizer under the system. Temperature measured in detail the relationship between the foam decay time, decay time and the recording of the bubble foam volume data. By coating a portion of viscometer measured the viscosity of foaming system.Experimental results show that the temperature 75 ℃, use PEG2000 as a crosslinking agent, when concentration of PAAc foam stabilizer is 1:8, foam has better stabilization performance. Half of the bubbling liquid and the relationship between temperature and found to meet the exponential relationship. Decay time of the foam and the foam volume data were fitted, the reaction of a bubble into the exponential decay changes. By discussing fo