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An XPS study for mechanisms of arsenate adsorption onto a magnetite-doped activated carbon fiber.pdf

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An XPS study for mechanisms of arsenate adsorption onto a magnetite-doped activated carbon fiber

Journal of Colloid and Interface Science xxx (2009) xxx–xxx ARTICLE IN PRESSContents lists available at ScienceDirect Journal of Colloid and Interface Science www.elsevier .com/locate / jc isAn XPS study for mechanisms of arsenate adsorption onto a magnetite-doped activated carbon fiber Shujuan Zhang a,b,c, Xiao-yan Li a, J. Paul Chen c,* a Environmental Engineering Research Centre, Department of Civil Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong, China bClemson University, 342 Computer Court, Anderson, SC 29625, USA cDepartment of Environmental Science and Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260, Singapore a r t i c l e i n f oArticle history: Received 11 August 2009 Accepted 1 November 2009 Available online xxxx Keywords: Arsenate Activated carbon fiber (ACF) Adsorption Magnetite X-ray photoelectron spectroscopy (XPS)0021-9797/$ - see front matter 2009 Elsevier Inc. A doi:10.1016/j.jcis.2009.11.001 * Corresponding author. Fax: +65 6872 5483/+1 83 E-mail addresses: jchen.enve97@, ese Please cite this article in press as: S. Zhang et aa b s t r a c t The surface and bulk structures of a newly developed carbon-based iron-containing adsorbent for As(V) adsorption were investigated by using X-ray diffraction (XRD), field emission scanning electronic micros- copy (FESEM), and X-ray photoelectron spectroscopy (XPS). XRD patterns of the adsorbents indicated that the modified activated carbon fiber (MACF) was a simple mixture of the raw activated carbon fiber (RACF) and magnetite. After modification, a porous film was formed on the surface of the MACF with nano-sized magnetite on it. The As(V) uptake on the MACF was highly pH dependent and was facilitated in acidic solutions. XPS studies demonstrated that the surface oxygen-containing functional groups were involved in the adsorption and that magnetite played a key role in As(V) uptake. The dominance of HAsO24 in sur- face complexes and the pH effect