二成分系混合冷媒r-290600aの臨界域における.docVIP

二成分系混合冷媒R-290/600aの臨界域における飽和密度の測定 MEASUREMENTS OF SATURATION DENSITIES FOR THE BINARY R-290/600a SYSTEM IN THE CRITICAL REGION ○ 樺山逸平　（慶大院）　坂部貴志　（慶大）　山本修治（慶大院） 佐藤春樹　（慶大理工）　渡部康一 ○ Ippei KABAYAMA, Takashi SAKABE, Shuji YAMAMOTO, Haruki SATO, and Koichi WATANABE Department of System Design Engineering, Keio University, 3-14-1, Hiyoshi Kohoku-ku, Yokohama 223-8522, Japan Corresponding author’s Tel: 045-566-1729, Fax: 045-566-1720, Email: hasato@sd.keio.ac.jp Hydrocarbons including R-290 and R-600a are the prospective candidates to replace R-12 (dichloro-difluoromethane) and R-134a (1,1,1,2-tetrafluoroethane). Those are called as natural refrigerants and considered as environmentally-benign alternative-refrigerants because of their zero ozone-depletion-potential (ODP) values and negligible global-warming-potential (GWP) values. In order to evaluate the possible application of these natural refrigerants in refrigeration and air-conditioning systems, it is essential to reveal their thermodynamic properties in detail. The critical parameters are the most important properties that we can predict thermodynamic and transport properties through modelings such as the law of corresponding state. We measured the saturated-vapor and saturated-liquid densities in the critical region as well as the critical temperature and density of each refrigerant. The critical temperatures and densities were determined for 25, 50 and 75 mass % of R-290 by measuring saturation densities near the critical point. In the case of the binary R-290/600a system, we measured 8 saturation densities both in liquid and gaseous phases near the critical point at composition of 25 mass % R-290. The experimental uncertainties of saturation temperature and density measurements were estimated to be within ± 10 mK and ± (0.4 to 1.7) kg?m-3. The purity of the samples used for the present measurements is 99.99 area % for R-290 and R-600a according to the analysis made by the manufacturer. On the basis of these measu