Au PDDA 石墨烯自组装.pdf

DOI: 10.1021/la100575g 11277Langmuir 2010, 26(13), 11277–11282 Published on Web 03/16/2010 /Langmuir ? 2010 American Chemical Society Self-Assembly of Cationic Polyelectrolyte-Functionalized Graphene Nanosheets and Gold Nanoparticles: A Two-Dimensional Heterostructure for Hydrogen Peroxide Sensing Youxing Fang, Shaojun Guo, Chengzhou Zhu, Yueming Zhai, and Erkang Wang* State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China, and Graduate School of the Chinese Academy of Sciences, Beijing, 100039, People’s Republic of China Received February 8, 2010. Revised Manuscript Received March 7, 2010 Wedemonstrate the use of cationic polyelectrolyte poly(diallyldimethyl ammonium chloride) (PDDA) functionalized graphene nanosheets (GNs) as the building block in the self-assembly ofGNs/Au nanoparticles (NPs) heterostructure to enhance the electrochemical catalytic ability. To ensure the GNs were modified with PDDA successfully, we study the PDDA/GNswith atomic forcemicroscopy (AFM) and zeta potentialmeasurements on the roughness and zeta potential changes relative to those of unmodified GNs, respectively. Then, the citrate-capped Au NPs are employed as the other model particles to construct two-dimensional GNs/NPs heterostructure. Here, the use of PDDA modifiers not only alters the electrostatic charges of graphene, but also probably provides a convenient self-assembly approach to the hybridization of graphene. Furthermore, we employ the high-loading Au NPs on graphene (GN/Au-NPs) as the electrochemical enhanced material for H2O2 sensing (as the model analyte). The wide linear ranges and low detection limits are obtained using the chronoamperometry technique at the GN/Au-NPs-modified glassy carbon electrode. Introduction Graphene, a one-atom thick and two-dimensional closely packed honeycomb lattice, has received numerous investigations fromboth the experimental and theoretical sc