Complex formation of ionic liquid surfactant and -cyclodextrin离子液+环糊精.pdf

下载文档

7
0
约2.48万字
约 6页
2017-04-11 发布于江苏
举报
版权申诉
保障服务

Complex formation of ionic liquid surfactant and -cyclodextrin离子液+环糊精.pdf

1、本文档共6页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。

Complexformationofionicliquidsurfactantand-cyclodextrin离子液环糊精

Aw s w s i c s i ? K 1 e c ( ( a f f c o t a c F a i 0 dColloids and Surfaces A: Physicochem. Eng. Aspects 292 (2007) 196–201 Complex formation of ionic liquid surfactant and -cyclodextrin Na Li a, Jie Liu b, Xueyan Zhao a, Yan’an Gao a, Liqiang Zheng a,?, Jin Zhang a, Li Yu a a Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China b Department of Chemistry, Liaocheng University, Liaocheng, China Received 25 February 2006; received in revised form 23 June 2006; accepted 23 June 2006 Available online 30 June 2006 bstract An ionic liquid (IL) surfactant, 1-dodecyl-3-methylimidazolium hexafluorophosphate (C12mimPF6) can form the inclusion complexes (ICs) ith -cyclodextrin (-CD). The surface tension measurements revealed that there were two kinds of inclusion formations, 1:1 and 1:2 (-CD/IL) toichiometry for -CD-C12mimPF6 ICs. The inclusion complexation interaction was further confirmed by FT-IR spectra. The inclusion compound as also characterized by Powder X-ray diffraction (XRD), 13C CP/MAS NMR, 2D 1H-1H COSY and TGA. The results showed that the host–guest ystem presented a channel type structure and each glucose unit of -CD was in a similar environment. Only the tails of C12mimPF6 were included nto the cavity of -CD. The formation mechanism of the -CD-C mimPF was also discussed. It was suggested that hydrophobicity played a12 6 rucial role in supporting the formation of -CD-C12mimPF6 ICs and hydrogen bonding was dispensable to maintain the channel type crystal tructure. The weak hydrophobic driven force made the -CD-C12mimPF6 unstable, which was reflected by TGA curves. In addition, possible nclusion structures of -CD-C12mimPF6 were speculated. 2006 Elsevier B.V. All rights reserved. h s m i T o m t b g t t p i feywords: -Cyclodextrin; Ionic liquid; Inclusion complexes; Surfactant . Introduction Cyclodextrins (CDs) are cyclic oligosaccharides of six to ight glucose units linked -1,4-linkag