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Linear Solvation Energy Relationship Analysis of Liquid-Liq Distribution Constants of 8-Hydroxyqu.pdf

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Linear Solvation Energy Relationship Analysis of Liquid-Liq Distribution Constants of 8-Hydroxyqu

Published: October 17, 2011 r 2011 American Chemical Society 3971 dx.doi.org/10.1021/je2003397 | J. Chem. Eng. Data 2011, 56, 3971–3983 ARTICLE pubs.acs.org/jced Linear Solvation Energy Relationship (LSER) Analysis of LiquidLiquid Distribution Constants of 8-Hydroxyquinoline and Its Derivatives Waldemar Robak,? Wieszaw Apostoluk,*,? and Katarzyna Ochromowicz? ?Military Engineering and CBRN Training Centre, Obornicka 108, 51-114 Wroczaw, Poland ?Hydrometallurgy Group, Division of Chemical Metallurgy, Wroczaw University of Technology, Wybrze_ze Wyspianskiego 27, 50-370 Wroczaw, Poland ABSTRACT:The linear solvation energy relationship (LSER) analysis of liquidliquid distribution constants of 8-hydroxyquinoline and its derivatives has been performed in terms of hydrophobicity of solutes, property parameters of diluents in the organic phase, and ionic strength of the aqueous phase. The effect of temperature has been also discussed. The obtained correlations permit the evaluation of unknown values of distribution constants of 8-hydroxyquinoline and/or its derivatives in the given extraction system. The set of available systematic experimental data reflects only the effect of temperature on the distribution of 8-hydroxyquinoline and its 2-methyl derivative; however, the distribution constants of the other 8-hydroxyquinolinols were determined sporadically at the different ionic strengths of the aqueous phase and lower or higher temperatures than 298 K. The correlation describing the effect of temperature can be used for the raw estimation of unknown values of distribution constants of 8-hydroxyquinoline and/or its derivatives in the given extraction system within the temperature range from (20 to 50) C. 1. INTRODUCTION 8-Hydroxyquinoline and its derivatives are known as che- lating ligands, forming stable complexes with a great number of metal ions. In chemical analysis, 8-hydroxyquinoline and its alkyl and/or halogen-substituted derivatives of different hy- drophobicit