聚苯胺论文：聚苯胺-碳复合材料的制备与储能应用聚苯胺论文：聚苯胺-碳复合材料的制备与储能应用.docVIP

聚苯胺论文：聚苯胺/碳复合材料的制备与储能应用 【中文摘要】电化学超级电容器(ESC)是近年来发展起来的一种介于传统电容器和蓄电池之间的一种新型储能元件,它具有比容量高、充放电速率快、效率高,对环境无污染,循环寿命长,使用范围广等特点。电极材料的选择对电化学电容器的制备至关重要,将碳材料与聚苯胺复合可以克服彼此的缺点,并能大大提高比容量。本文主要研究了聚苯胺/碳复合材料的制备及电化学性能。并采用透射电镜、扫描电镜等测试手段,对材料形貌进行了表征；采用循环伏安、恒电流充放电、循环寿命等电化学测试手段来测试材料的电化学性能。具体研究内容如下：1.对ACF浸渍催化剂处理,然后通过化学气相沉积法(CVD)在ACF表面原位生长CNT,得到ACF/CNT复合材料,再与聚苯胺(PANI)复合,制备出CNT/ACF/PANI复合材料,通过电化学性能测试表明,CNT/ACF/PANI复合材料具有比容量大,循环稳定性好等特点,其比容量可达到158.5F·g-1(有机电解液)。2.分别采用过滤法、界面静置法和喷涂法,将粉末状的CNT制备成碳纳米管网前驱体,探究各种因素对其导电性和力学性能的影响,确定最佳的制备方案。3.对碳纳米管网前驱体进行一系列的后续处理,得到碳纳米管网,再分别与聚苯胺复合,制得聚苯胺/碳纳米管网前驱体复合材料和聚苯胺／碳纳米管网复合材料,电化学性能测试表明,聚苯胺/碳纳米管网复合材料具有更大的比容量、更稳定的循环性能等特性,聚苯胺/碳纳米管网复合材料的比容量可达到143.2 F·g-1(有机电解液)。 【英文摘要】In recent years, Electrochemical Super Capacitor (ESC) has been developing as a kind of new focused energy storage devices for their novel properties. These properties include high specific capacity, quick charging and discharging rate, high efficiency, environmental friendly, long life cycle and widely using fields. Electrode material selection is critical to the preparation of electrochemical capacitor, preparing carbon material and Polyaniline to be composite material could conquer the disadvantages of each other, and increase the specific capacitance.This paper mainly studied the preparation of polyaniline/carbon composites and their electrochemical properties. Morphology of the obtained composites were characterized by transmission electron microscope and scanning electron microscopy, and the electrochemical performances of the obtained materials were tested by the cyclic voltammograms, galvanostatic charging/discharging, cycles life. Specific studies are as follows:1. First, ACF was immersed in the catalyst solution, and then situ grew CNT on the surface of ACF by chemical vapor deposition(CVD), which obtained the ACF/CNT composite, at last the CNT/ACF/PANI composite was prepared by compounding the obtained material with polyaniline(PANI). The