BiWO6-C3N4光催化.pdf

N d L D a A R R A A K g B P F S 1 i g s b t g s m c p l C a s h a r a 0 dApplied Catalysis B: Environmental 108– 109 (2011) 100– 107 Contents lists available at ScienceDirect Applied Catalysis B: Environmental journa l h o me pa ge: www.elsev ier .com/ locate /apcatb ovel visible light-induced g-C3N4/Bi2WO6 composite photocatalysts for efficient egradation of methyl orange ei Ge ?, Changcun Han, Jing Liu epartment of Materials Science and Engineering, College of Science, China University of Petroleum Beijing, No. 18 Fuxue Rd, Beijing 102249, PR China r t i c l e i n f o rticle history: eceived 31 May 2011 eceived in revised form 12 August 2011 ccepted 12 August 2011 vailable online 19 August 2011 eywords: -C3N4 a b s t r a c t Novel visible light-induced g-C3N4/Bi2WO6 composite photocatalysts were synthesized by introduc- ing polymeric g-C3N4. The obtained g-C3N4/Bi2WO6 products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, ultraviolet–visible diffuse reflection spectroscopy (DRS), and photoluminescence spec- troscopy. The DRS results revealed that the g-C3N4/Bi2WO6 samples had a red shift and strong absorption in the visible light region. The photocatalytic oxidation ability of the novel photocatalyst was evalu- ated using methyl orange as a target pollutant. The photocatalysts exhibited a significantly enhancedi2WO6 hotocatalysis unctional emiconductors photocatalytic performance in degrading methyl orange. The optimal g-C3N4 content for the photocat- alytic activity of the heterojunction structures was determined. The synergic effect between g-C3N4 and Bi2WO6 was found to lead to an improved photo-generated carrier separation. Consequently, the photo- catalytic performance of the g-C3N4/Bi2WO6 composites under visible