CC2012暨南大学刘应亮-水热碳化壳聚糖一步法合成氨基功能化荧光碳纳米粒子-附录.pdf

Supplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry 2011 Supplementary Information One step synthesis amino-functionalized fluorescent carbon nanoparticles by hydrothermal carbonization chitosan Yunhua Yang,a Jianghu Cui,a Mingtao Zheng,b Chaofan Hu,a Shaozao Tan,a Yong Xiao,a Qu Yanga and Yingliang Liu*a a Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632, China, E-mail: tliuyl@jnu.edu.cn b College of Science, South China Agricultural University, Guangzhou 510642, China Electronic Supplementary Material (ESI) for Chemical Communications This journal is ? The Royal Society of Chemistry 2011 Supplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry 2011 Experimental Section 1. Preparation of the fluorescent carbon nanoparticles (CNPs) In a typical procedure, amino-functionalized fluorescent carbon nanoparticles were synthesized as follows: 2 g chitosan was dissolved in 18 mL 2% acetic acid solutions and then the mixture was sealed into a Teflon equipped stainless steel autoclave, which was then placed in a muffle furnace followed by hydrothermal treatment at 180℃ for 12 h. A programmed temperature profile was adopted to control the heating process. The heating rate was set at 5 ℃?min-1. After the reaction, the autoclave was cooled down naturally. The obtained dark brown solution was centrifuged at a high speed (24 000 g) for 15 min to remove the less-fluorescent deposit. The upper brown solution have an average size of 5 nm and exhibits strong blue luminescence under excitation at 365 nm. The deposit nanoparticles have a larger diameters in the range of 30-40 nm and exhibits very weak fluorescence after ultrasonic disperse in water. Pure upper brown luminescent carbon nanoparticles obtained by freeze dried was named as CNPs and had a yield of 7.8%. 2. Char