IrZSM-5cordierite monolith for catalytic NOx reduction from automobile exhaust.pdfVIP

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IrZSM-5cordierite monolith for catalytic NOx reduction from automobile exhaust.pdf

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IrZSM-5cordierite monolith for catalytic NOx reduction from automobile exhaust

Available online at /locate/catcom Catalysis Communications 9 (2008) 409–415Ir/ZSM-5/cordierite monolith for catalytic NOx reduction from automobile exhaust Landong Li a,b, Fuxiang Zhang a, Naijia Guan a,* a Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, PR China b Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing 100085, PR China Received 19 December 2006; received in revised form 7 April 2007; accepted 10 April 2007 Available online 30 April 2007Abstract Ir/ZSM-5/cordierite was studied as promising catalyst for the reduction of nitrogen oxides from automobile exhaust under both stoi- chiometric combustion and lean conditions. ZSM-5 was in situ synthesized on the surface of honeycomb cordierite substrate and iridium was introduced to ZSM-5/cordierite by wet impregnation. Under stoichiometric combustion, Ir/ZSM-5/cordierite exhibited good cata- lytic activity approaching commercial three-way catalysts, and the three main pollutants nitrogen oxides, carbon monoxide and unburned hydrocarbons could be purified simultaneously. Under lean conditions, Ir/ZSM-5/cordierite also exhibited quite good deNOx activities though excess oxygen showed inhibition effect on NOx reduction. 2007 Elsevier B.V. All rights reserved. Keywords: Ir/ZSM-5/cordierite; Automobile exhaust; NOx1. Introduction The automobile exhaust contains various pollutants: nitrogen oxides, carbon monoxide, unburned hydrocar- bons and so on. One of the most urgent problems is the removal of nitrogen oxides, which greatly contribute to the formation of photochemical smog and acid rain [1]. Based on noble metal Pt, Pd and Rh as main active ingre- dients, three way catalysts (TWC) can provide high level of emission control for nitrogen oxides, carbon monoxide and unburned hydrocarbons. Up to now, TWC have been proved to be efficient and reliable [2,3], and considered as optimal means to treat the exhaust unde