铋层状结构铁电体的进展探究.pdfVIP

第 29卷 第 5期 无 机 材 料 学 报 Vol. 29 No. 5 2014年 5月 Journal of Inorganic Materials May, 2014 收稿日期: 2013-12-19; 收到修改稿日期: 2014-01-23 基金项目: 国家自然科学基金重点项目; 国际科技部 973项目(2009CB613305) National Natural Science Foundation of China ; The Ministry of Science and Technology Project 973(2009CB613305) 作者简介: 张发强(1986?), 男, 博士研究生. E-mail: zhangfq@student.sic.ac.cn 通讯作者: 李永祥, 研究员. E-mail: yxli@mail.sic.ac.cn 文章编号: 1000-324X(2014)05-0449-12 DOI: 10.3724/SP.J.1077.2014.13669 铋层状结构铁电体的研究进展 张发强 1, 2, 李永祥 1 (1. 中国科学院 上海硅酸盐研究所, 信息功能材料与器件研究中心, 上海 200050; 2. 中国科学院大学, 北京 100049) 摘 要: 铋层状结构铁电体 (BLSF) 作为一种类钙钛矿无铅铁电压电材料, 由于其在高温、高频以及非易失性铁电 随机存储器等领域具有突出的综合优势, 因而受到广泛关注。本文以 BLSF的综合特征为基础, 对其结构设计和微 结构研究中存在的问题进行了详细探讨, 并重点总结了近二十年来其在性能优化和薄膜制备中取得的进展。此外, 本文还对一些以铁电为背景的新的研究方向做了介绍。最后提出了 BLSF在未来发展中值得关注的几个重要问题。 关 键 词: 铋层状结构; 铁电体; 无铅压电陶瓷; 非易失性铁电随机存储器; 综述 中图分类号: TQ174 文献标识码: A Recent Progress on Bismuth Layer-structured Ferroelectrics ZHANG Fa-Qiang1, 2, LI Yong-Xiang1 (1. The Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China) Abstract: As an improtant lead-free ferroelectric/piezoelectric system, the past few decades have attracted in- creasing attention of bismuth layer structured-ferroelectrics (BLSF) due to its comprehensive advantages in the ar- eas of high temperature, high frequency and ferroelectric random access memory (FRAM). In this paper, the recent progresses on the study of this system were reviewed. Firstly, as the basic of other researches, the key issues in strucutre design and microstructure study were dicussed in detail. Then special emphasis was put on ferroelectric/ piezoelectric performance and film technology. Additionally, some new research fields that were closely related to ferroelectric were introduced. In the end, the research