全水发泡在阻燃聚氨酯硬泡中的应用研究毕业论文.docVIP

毕业论文  PAGE 17 高分子材料与工程毕业论文 专业：高分子材料与工程　 题目：全水发泡在阻燃聚氨酯硬泡中的应用研究 摘要 采用多元醇、异氰酸酯、催化剂、发泡剂和阻燃剂等为原料制备了全水发泡阻燃聚氨酯硬质泡沫（PURF），讨论了聚醚多元醇种类、催化剂、发泡剂、异氰酸酯指数以及阻燃剂对聚氨酯硬质泡沫性能的影响。结果表明 ，聚酯多元醇能够改善泡孔结构 ，但降低压缩强度和尺寸稳定性；不同催化剂复配 ，可以控制发泡工艺;水发泡剂与泡沫的密度、泡孔结构、力学性能有关；异氰酸酯指数在1.1～1.2时 ，泡沫的压缩强度、尺寸稳定性等较好;三(2-氯异丙基) 磷酸酯(TCPP)可赋予聚氨酯硬质泡沫一定的阻燃性，但对泡体结构、压缩强度和尺寸稳定性有影响。 关键词：聚氨酯硬??泡沫，全水发泡，阻燃性能 ABSTRACT The water-blown rigid polyurethane flame-retardant foam(PURF) was prepared by polyol, isocyanate , catalyst ,blowing agents and flame retardants as raw materials,in this pape. The types of polyrther polyols, catalysts, blowing agents,isocyanate index and fire retardant on the PURF performance were investgated. The results show that the polyester polyol can improve the cell structure, but reduce the compression strength and dimensional stability; different catalyst compound, can control the foaming process; water foaming agent and foam density, cell structure, the mechanical properties; isocyanate index of 1.1 to 1.2, the foam compression strength, good dimensional stability, etc.; Tris-(2-chloroisopropyl)phosphate phosphate (TCPP) flame retardant may be given to PURF certain, but on the bubble structure, compressive strength dimensional stability, and impact. Keywords：Rigid Polyurethane Foam,Water-blown, Flame retardant  目 录  TOC \o 1-3 \h \z \u  HYPERLINK \l _Toc262726034 摘要  PAGEREF _Toc262726034 \h I  HYPERLINK \l _Toc262726035 ABSTRACT  PAGEREF _Toc262726035 \h II  HYPERLINK \l _Toc262726036 第一章 前言  PAGEREF _Toc262726036 \h 1  HYPERLINK \l _Toc262726037 1.1 聚氨酯概况  PAGEREF _Toc262726037 \h 1  HYPERLINK \l _Toc262726038 1.1.1聚氨酯简介及其应用  PAGEREF _Toc262726038 \h 1  HYPERLINK \l _Toc262726039 1.2 聚氨酯的发展现状及趋势  PAGEREF _Toc262726039 \h 2  HYPERLINK \l _Toc262726040 1.3硬质聚氨酯泡沫塑料  PAGEREF _Toc262726040 \h 3  HYPERLINK \l _Toc262726041 1.3.1硬质聚氨酯泡沫塑料的性能特点  PAGEREF _Toc262726041 \h 3  HYPERLINK \l _Toc262726042 1.3.2聚氨酯泡沫塑料的制