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氢、碱金属和碱土金属
氢、碱金属和碱土金属Chapter 10 Hydrogen , Alkali and Alkali-earth metals;§10-1氢及其化合物(Hydrogen ant its compounds);(2)存在:H:D=6800:1(原子个数) H:T=1e10:1; (4) 氢同位素形成的单质H2、D2、T2,在化学性质上
完全相同,但物理性质(熔沸点)上有差别。
2. Properties:
(1) Physical properties:
H2:极难溶于水和有机溶剂,可以贮存在金属(Pt、Pd)和合金(LaNi5)中
固态氢(黑色)又称为金属氢:在晶格质点上为质子,而电子为整个晶体享,所以这样的晶体具有导电性,固态氢可能为立方或六方分子晶格。
; (2)Chemical properties:
a. 成键特点:电子构型为 1s ,可以放在ⅠA类,
但第一电离势高于碱金属的第一电离势;也可放在
ⅦA类。
b. 化合反应:与金属: 2Na + H2 = 2NaH
Ca + H2 = CaH2
与非金属: H2 + F2 = 2HF
c. 还原反应: CuO + H2 = Cu + H2O
WO3 + 3H2 = W + 3H2O ; 3.Preparation
(1) 实验室:
(2)工业上:;§10-2碱金属元素及其化合物
Alkali metals and their compounds
Lithium Sodium Potassium
Li Na K
Rubidium Cesium Francium
Rb Cs Fr
;for structural and mechanistic studies of ion channels ;;I was born on February 19, 1956 in the middle of a snowstorm. It remains one of those humorous family stories that my mother likes to tell. My father the planner had rehearsed the way to the hospital but apparently things looked a lot different at night in a blizzard. Eventually they made it and so did I, the fourth of seven children. My father was a postal worker when I was very young but studied computers and became a programmer on the big IBM main frames. My mother worked as a part time schoolteacher, but mostly took care of the children at home. Thinking back on it now I know we did not have much money but I never knew that growing up. My parents provided a happy environment and made their expectations clear to us. Television is bad for you, reading is good for you, and you better get an A for effort in school. What you end up doing in life is up to you. Just make sure you enjoy what you do because then you will do it well. We all pursu
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