水溶性有机羧酸醇铵盐防锈剂的分子结构与性能关系的研究_蒋海珍.pdf

2005年 3月 润滑与密封 M ar.2005 第 2期 (总第 168期 ) LUBR ICAT ION ENG INEER ING N o.2(serialN o.168) 水溶性有机羧酸醇铵盐防锈剂的分子结构与性能关系的研究 蒋海珍 1, 2 　陶德华 1 　王 　彬 1 (1. 上海大学润滑化学研究室 　上海 200072;2. 上海大学理学院 　上海 200436) 摘要:合成并研究了水溶性有机羧酸醇铵盐类防锈剂 , 系统地考察了烷链的长度 、 极性基团、 羧基的个数对防锈性 能和溶解度的影响 。 根据最佳的分子结构组合 , 设计并合成了与 C iba公司的同类产品性能相 当的水溶性有机羧酸醇铵 盐 ATEA-1。 关键词 :防锈性 ;羧酸醇铵盐 ;极性基团 ;水溶性 中图分类号 :TG 501.5;TE626.3　文献标识码:A　文章编号 :0254 - 0150 (2005) 2 - 072 - 3 Study ofRelations between theM olecular Structures and the Rust- inh ib iting Properties on Aqueous Solub leO rgan ic Acid Salts J iang Haizhen1, 2 　Tao Dehua1 　W ang B in1 (1. Research Laboratory of Lubrication Chem istry, Shanghai University, Shanghai 200072, Ch ina; 2. Science Institute of Shanghai University, Shanghai 200436, Ch ina) Abstract:A series of aqueous solub le anti-rust additives of alipha tic acid ethanolam ine salts were synthesized and stud- ied. The effects of the leng th of alkyl-chain, the polar group and the number of carboxy lg roup on rust-inhibiting properties and solubility were investigated in system atically. A nove lATEA -1 of aqueous so luble aliphatic acid ethano lam ine saltwas designed and synthesized according to the optimum com bination of the m olecular structure, which has outstanding rust-in- hibiting property, sim ilar as the product of Ciba company in rust-inhibiting property. K eyword s:rust-inhibiting property;polar group;acid e thano lam ine salt;so lubility 　 防锈剂是水基切削液及水基润滑剂中的一种重要 锈剂 , 分子中不但要有起防锈作用的极性基团 , 而且 添加剂 。过去广