南港60万吨 年碳四综合利用项目 Abstract.pdfVIP

Nangang 600 kt/a C4 comprehensive utilization project Abstract 1. Introduction The project brought about a way of utilizing the novel technology to convert low value C4 chemicals that are used as fuel to high value-added products: ? Double-effect distillation technology is adopted to separate manufacture gas from oil refinery into isobutane and olefin components; ? Olefins metathesis is adopted, producing high value propylene consuming small quantity of ethylene and byproduct hexene mixture used to produce etherified gasoline; ? Halcon process is adopted for preparation of propylene oxide with isobutane and propylene. PO Isobutane Oxidation Isobutene C4 Mixture Separetion - C4 Olefins Pre Propylene Ethylene Metathesis Hexene Gasoline Ethering Figure 1 Technology schematic diagram In designing the project, we stuck to the principle of atomic economy and green chemistry, and achieved an atom utilization of near 100% of C4 material, which meets the demand of the market. This will promote the comprehensive utilization of C4 hydrocarbon. The technologies adopted in the project have demonstrated successful Figure 2 Plant effect picture Abstract