离子交换膜分离机制的理论分析.pdfVIP

Advances in Environmental Protection 环境保护前沿, 2016, 6(2), 7-12 Published Online April 2016 in Hans. /journal/aep /10.12677/aep.2016.62002 Analysis of the Separation Mechanism of Ion Exchange Membrane Yazhou Peng, Dehua Xie, Bozhi Ren Faculty of Civil Engineering, Hunan University of Science and Technology, Xiangtan Hunan Received: Mar. 19th, 2016; accepted: Apr. 3rd, 2016; published: Apr. 7th, 2016 Copyright ? 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract This paper, based on Donnan dialysis and chemical potential equilibrium principle, theoretically investigates the three states of ion exchange membrane without external supply of electricity: the rate of ion transport is slow thus is the deterministic step, while the transport in the boundary layer is rapid and much faster than that in the membrane; the transport rate in the membrane is much faster than that in the boundary layer, which is the deterministic step; both the transport rates in membrane and boundary layer are the deterministic steps. And in this paper, the three states are discussed and the conclusion is reached that assuming temperature, pressure and other influential factors remains constant, among the three states mentioned above, the first state is suitable when the concentration of driving ion and feed ion is very high, the second is suitable when the concentration of the two ions is very low and the third is suitable when the concentra- tion is medium. The relationship between the range of concentration and its cor