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FactsandFiguresaboutCatalystsLifecycleontheearth.ppt
Facts and Figures about Catalysts
Life cycle on the earth
Catalysts (enzyme) participates most part of life cycle
e.g. forming, growing, decaying
Catalysis contributes great part in the processes of converting sun energy to various other forms of energies
e.g. photosynthesis by plant CO2 + H2O=HC + O2
Catalysis plays a key role in maintaining our environment
Chemical Industry
ca. $2 bn annual sale of catalysts
ca. $200 bn annual sale of the chemicals that are related products
90% of chemical industry has catalysis-related processes
Catalysts contributes ca. 2% of total investment in a chemical process ; Catalysis
Catalysis is an action by catalyst which takes part in a chemical reaction process and can alter the rate of reactions, and yet itself will return to its original form without being consumed or destroyed at the end of the reactions
(This is one of many definitions)
Three key aspects of catalyst action
taking part in the reaction
it will change itself during the process by interacting with other reactant/product molecules
altering the rates of reactions
in most cases the rates of reactions are increased by the action of catalysts; however, in some situations the rates of undesired reactions are selectively suppressed
Returning to its original form
After reaction cycles a catalyst with exactly the same nature is ‘reborn’
In practice a catalyst has its lifespan - it deactivates gradually during use;Catalysis action - Reaction kinetics and mechanism
Catalyst action leads to the rate of a reaction to change.
This is realised by changing the course of reaction (compared to non-catalytic reaction)
Forming complex with reactants/products, controlling the rate of elementary steps in the process. This is evidenced by the facts that
The reaction activation energy is altered
The intermediates formed are different from
those formed in non-catalytic reaction
The rates of reactions are altered (both
desired and undesired ones)
Reactions proceed under l
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