Si改性对V2O5WO3-TiO2催化剂NH3-SCR活性和热稳定性的影响.pdfVIP

Chinese Journal of Catalysis 37 (2016) 1340–1346 催化学报 2016年 第37卷 第8期 |   a v a i l a b l e   a t  www . s c i e n c e d i r e c t . c om   j o u r n a l   h omep a g e :  www . e l s e v i e r . c om / l o c a t e / c h n j c   Article    Effects of silica additive on the NH3‐SCR activity and thermal stability of a V2O5/WO3‐TiO2 catalyst Xuesong Liu a,b, Xiaodong Wu a,b,*, Tengfei Xu a, Duan Weng a,b,#, Zhichun Si b, Rui Ran a a Key Laboratory of Advanced Materials of Ministry of Education, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China b Advanced Materials Institute, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, Guangdong, China A R T I C L E I N F O   A B S T R A C T Article history: Received 4 February 2016 Accepted 14 April 2016 Published 5 August 2016   V2O5/WO3‐TiO2 and V2O5/WO3‐TiO2‐SiO2 catalysts were prepared by a wetness impregnation method, and both the catalysts were hydrothermally aged at 750 C in 10 vol% H2O/air for 24 h. The catalysts were evaluated for NOx conversion using NH3 as the reductant. Hydrothermal ageing decreased the NOx conversion of V2O5/WO3‐TiO2 catalyst severely over the entire measured tem‐perature range. Interestingly, the NH3‐SCR activity of the silica‐modified catalyst at 220–480 C is enhanced after ageing. The catalysts were characterized by X‐ray diffraction, nitrogen adsorption, X‐ray fluorescence, Raman spectroscopy, H2 temperature‐programmed reduction, and NH3 temper‐ature‐programmed desorption. The addition of silica inhibited the phase transition from anatase to rutile titania, growth of TiO2 crystallite size and shrinkage of catalyst surface area. Consequently, the vanadia species remained highly dispersed and the hydrothermal stability of the V2O5/WO3‐TiO2catalyst was significantly improved. © 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences.Published by Elsevier B.V. All righ