H6P2W18O62高岭土的制备、表征及催化合成乙酰水杨酸.pdfVIP

2014 年第 33 卷第 5 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1205· 化 工 进 展 H6P2W18O62/高岭土的制备、表征及催化合成乙酰水杨酸 曹小华 1，王原平 2，徐常龙 1，雷艳虹 1，占昌朝 1 （1 九江学院化学与环境工程学院，江西 九江 332005；2九江职业大学，江西 九江 332000） 摘要：以高岭土为载体，Dawson 结构磷钨酸（H6P2W18O62·13H2O）为活性组分制备了负载型催化剂 H6P2W18O62/ 高岭土，并通过 FT-IR、XRD、SEM 和 EDS 对催化剂进行表征。以催化合成乙酰水杨酸为探针反应，考察了催 化剂的酸催化性能。结果表明，在优化反应条件为 H6P2W18O62负载量为 40%，w(H6P2W18O62/高岭土)=7.2%（基 于水杨酸的质量），反应温度为 90℃，反应时间为 40min 时，乙酰水杨酸收率达 90.2%，催化剂重复使用 5 次， 乙酰水杨酸收率仍可达到 85.1%。该催化剂具有价廉易得、催化活性高、后处理工艺简单、不腐蚀设备、无环境 污染、可重复使用等优点。 关键词：H6P2W18O62/高岭土；乙酰水杨酸；载体；催化；酯化 中图分类号：TQ 426.6 文献标志码：A 文章编号：1000–6613（2014）05–1205–06 DOI：10.3969/j.issn.1000-6613.2014.05.021 Preparation and characterization of H6P2W18O62/Kaolin and its activity on the catalytic synthesis of acetylsalicylic acid CAO Xiaohua1，WANG Yuanping2，XU Changlong1，LEI Yanhong1，ZHAN Changchao1 （1College of Chemistry and Environmental Engineering，Jiujiang University，Jiujiang 332005，Jiangxi，China；2Jiujiang Vocational University，Jiujiang 332000，Jiangxi，China） Abstract ： H6P2W18O62/kaolin was fabricated by dipping Kaolin in the mixing solution of phosphotungstic acid with Dawson structure，and characterized by FT-IR，XRD，SEM and EDS. The catalytic synthesis of acetylsalicylic was carried out as a probe reaction to study the acid catalytic performance of the catalyst，under the optimal condition，i.e. the supported quantity of 40%，w (catalyst）= 7.2% (relative to the dosage of salicylic acid)，reaction temperature of 90℃，and reaction time of 40min. The average yield of acetylsalicylic acid reaches 90.2%. The catalyst shows good reusability. After its five time usage，the yield of acetylsalicylic acid was still above 85.1%. The catalyst is attractive for esterification by its low cost，high activity，simple post-treatment，no corrosion to the equipment and no pollution. Key words：H6P2W18O62/Kaolin；acetylsalicylic acid；support；catalysis；esterification 杂多酸是一类兼具酸性、氧化性及准液相行为 的绿色催化剂，在许多反应中表现出优异的催化性 能。