VPOTiN催化剂的制备、表征及催化氧化NO的实验研究.pdfVIP

第 35 卷 第 16 期 中 国 电 机 工 程 学 报 Vol.35 No.16 Aug. 20, 2015 2015 年 8 月 20 日 Proceedings of the CSEE ©2015 Chin.Soc.for Elec.Eng. 4131 DOI：10.13334/j.0258-8013.pcsee.2015.16.016 文章编号：0258-8013 (2015) 16-4131-08 中图分类号：X 511 VPO/TiN 催化剂的制备、表征及 催化氧化 NO 的实验研究 贾勇 1，杜大倩 1，丁希楼 1，丁杰 2，钟秦 2 (1．安徽工业大学能源与环境学院，安徽省 马鞍山市 243002； 2．南京理工大学化工学院，江苏省 南京市 210094) An Experimental Study of Preparation, Characterization and Catalytic Performance of VPO/TiN Catalyst for NO Oxidation JIA Yong1, DU Daqian1, DING Xilou1, DING Jie2, ZHONG Qin2 (1. School of Energy and Environment, Anhui University of Technology, Ma Anshan 243002, Anhui Province, China; 2. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu Province, China) ABSTRACT: The VPO/TiN catalysts were prepared by impregnation method. The structural characteristics of VPO/TiN catalysts and their catalytic activity for NO oxidation were also investigated. The results show that the catalytic activity of VPO/TiN catalysts calcined at 350 ℃ is best and the corresponding NO oxidation rate is 61.1%. N doping could promote the formation of oxygen vacancy on the surface of 0.1V(5)PO/TiN(1) catalysts, which also enhances the amount of chemisorbed oxygen (Oα) and catalytic oxidation activity of 0.1V(5)PO/TiN(1) catalysts. The amount of Brønsted acid sites reaches maximum when the mole ratio of P to V is 1/5. Combined with the analysis of activity tests, it could be conclude that Brønsted acid sites play an important role in catalytic oxidation of NO over 0.1V(5)PO/TiN(1) catalysts. The resistance to SO2 of 0.1V(5)PO/TiN(1) catalyst is superior and the oxidation rate of NO is above 55% at 300 ℃ when SO2 concentration is in the range of 0.02%~0.08%. There is no SO42− formed on 0.1V(5)PO/TiN(1) catalysts after reaction in the presence of SO2. The results also show that water vapour inhibits some oxidation of NO over 0.1V(5)PO/TiN(1) catalysts. KEY