离子组成对氧化石墨烯在饱和多孔介质中迁移行为的影响.pdfVIP

2015 年 4 月 CIESC Journal ·1484· April 2015 第 66卷 第 4期 化 工 学 报 Vol.66 No.4 离子组成对氧化石墨烯在饱和多孔介质中迁移行为的影响 姜雪辉，范伟，霍明昕，杨武，刘仲谋，周欢 (东北师范大学环境学院，吉林 长春 130117) 摘要：采用室内饱和石英砂柱一维渗流模拟实验，研究离子强度相同、离子组成（钠吸附比）不同的电解质溶液 对氧化石墨烯（GO）在地下环境中迁移行为的影响。通过测定 GO 穿透过程的沉积动力学曲线，结合数学模型与 界面化学理论，对其迁移沉积机理进行分析。结果显示，当钠吸附比从 0 增加到∞时，砂柱出流最大浓度升高， GO 回收率增加，穿透实验沉积速率、去除效率和吸附效率分别从 0.356 min−1、1.04×10−2、0.054 减小到 0.039 min−1、 1.1×10−3、0.003。研究认为布朗扩散是造成 GO 颗粒与石英砂粒相互接触的主要机制，Ca2+浓度变化是造成不同 钠吸附比环境下 GO 不同迁移行为的主要因素，其机理在于 Ca2+与 GO 发生电中和与桥接作用，改变了颗粒间的 静电斥力与引力平衡，进而影响了 GO 颗粒粒度与形态，并最终强化了砂柱对 GO 的截留效应。 关键词：氧化石墨烯；粒子；离子组成；多孔介质；迁移行为；模型 DOI：10.11949/j.issn.0438-1157 中图分类号：X 53 文献标志码：A 文章编号：0438—1157（2015）04—1484—07 Effect of cations composition on transport of graphene oxide in saturated porous media JIANG Xuehui, FAN Wei, HUO Mingxin, YANG Wu, LIU Zhongmou, ZHOU Huan (School of Environment, Northeast Normal University, Changchun 130117, Jilin, China) Abstract: This study was conducted on one-dimensional seepage in saturated porous media fixed on packed bed columns to investigate the fate of graphene oxide (GO) in the subsurface environment. In the present experiments, the fate of grapheme oxide (GO) was investigated as a function of cations composition (sodium absorption ratios, SAR) at 10 mmol·L−1 constant ionic strength (IS). To analyze the migration deposition mechanism of GO, the deposition kinetics curve was determined by mathematical model and interface chemistry theory. When SAR increased from zero to ∞, maximum effluent concentration of sand columns and recovery of GO increased, however, deposition rate, removal efficiency and attachment efficiency of the breakthrough experiments decreased respectively from 0.356 min−1 to 0.039 min−1 、1.04×10−2 to 1.1×10−3 and 0.054 to 0.003. Accordingly, it was proposed that Brownian diff