磷灰石在微生物浸铜体系的溶出特性及对浸铜效率的影响.pdfVIP

第 24 卷第 11 期 中国有色金属学报 2014 年 11 月 Volume 24 Number 11 The Chinese Journal of Nonferrous Metals November 2014 文章编号：1004-0609(2014)11-2928-07 磷灰石在微生物浸铜体系的溶出特性及对浸铜效率的影响 周闪闪1, 2，林 海1, 2，董颖博1, 2，许晓芳 摘 要：为了探明磷灰石在微生物浸出黄铜矿体系中的溶出特性及其对黄铜矿浸出的影响，选择粒径小于 43 μm 的磷灰石与粒径小于 74 μm的黄铜矿以及At.f菌组成矿浆浸出体系，考察不同At.f菌接种量对于磷灰石溶出速率的 影响及对黄铜矿浸出效果的影响。结果表明：浸出体系中含低浓度PO 1, 2 (1. 北京科技大学 金属矿山高效开采与安全教育部重点实验室，北京 100083； 2. 北京科技大学 土木与环境工程学院，北京 100083) 4 3−可以提高铜的浸出效率；当At.f菌接种量 为 5%时，微生物浸出体系中磷灰石溶出的PO43−浓度最小，为 0.62 mg/L，此时黄铜矿的最终浸出率最高，达到 57.4%，比PO43−溶液浓度最高时体系的铜浸出率提高近 30%。通过对微生物浸出前、后的浸渣进行扫描电镜、能 谱分析和XRD分析发现，浸出后磷灰石表面浸蚀不明显，而黄铜矿表面浸蚀明显，同时浸渣中有新物质铵黄铁矾 生成；磷灰石对于新生成的沉淀有一定的吸附作用，而且溶出较低浓度的PO43− Dissolution characteristics of apatite in chalcopyrite bioleaching system and its influence on chalcopyrite leaching efficiency ZHOU Shan-shan 体系能提高黄铜矿的 浸出。 关键词：黄铜矿；磷灰石；微生物浸出；At.f菌 中图分类号：TD925.5 文献标志码：A 1, 2, LIN Hai1, 2, DONG Ying-bo1, 2, XU Xiao-fang Abstract: To make sure the dissolution characteristics of apatite in the chalcopyrite bioleaching system and the influence on the chalcopyrite leaching efficiency, the apatite with particle size of less than 43 μm, chalcopyrite with 74 μm and Acidithiobacillus ferrooxidans (At.f) were used to prepare a bioleaching system. And the influence of different At.f inoculation amount on the apatite dissolution rate and chalcopyrite leaching effect were studied. The results show that chalcopyrite leaching efficiency can be improved when there exists PO 1, 2 (1. Key Laboratory of High-Efficient Mining and Safety of Metal Mines, Ministry of Education, University of Science and Technology Beijing, Beijing 100083, China; 2. School of Civil and Environmental Engineering，University of Science and Technology Beijing, Beijing 100083, China) 4 3− with low concentration in the bioleaching system. And PO43− reaches the lowest concentration of 0.62 mg/L in the bioleaching