采用特殊的相反转乳化剂制备水基环氧固化剂分散体.pdfVIP

第 卷 第 期 化 工 学 报 56 10 Vol. 56 No. 10 年 月 Z005 10 Jour nal of Che mical Industr y and Engi neeri ng (Chi na ) Oct ober Z005 妥 妥、 妥妥妥妥、 妥 研究快报 妥 、 妥 妥 妥 妥 、 妥 妥 Pr ePar ati on of aCueous di sPer si on of ePoxy curi n9 a9ent Wi t h sPeci al l y synt hesi zed Phase i nver si on emul si fi er 周继亮 涂伟萍 胡剑青 ZH OU Ji l i an9 ! #TU Wei Pi n9 ! #HU Ji anCi n9 ! (Sc hool of Che mical and Ener gy Engineering Sout h China Uniuersit y of Tec hnology Guangzhou 510640 Guangdong China ) Abstr act $Generall y t he curi ng agents f or aCueous a mbi ent-te mperat ure-cured epoXy resi n syste ms are epoXy-pol ya mi ne adduct Whi ch are rendered Water-sol ubl e by salti ng Wit h or gani c aci ds Whil e t hese aci ds have adverse i nfl uence on fil m pr opert y . It i s a trend t o devel op aCueous di spersi on of epoXy curi ng agent f ree of or gani c aci ds . The conventi onal surf actants are not suited t o act as phase i nversi on e mulsifi ers t o prepare aCueous di spersi on of epoXy-pol ya mi ne adduct. So a speci al phase i nversi on e mulsifi er TETA- DGEPG- EPON834 Was synt hesized i n t Wo steps . Firstl y di gl yci dyl et her of pol ygl ycol (DGEPG )Was used as t he chai n eXtender t o react Wit h tri et hyl enete tra mi ne (TETA )i n pr opyl ene gl ycol met hyl et her (P )at 70 f or about 4 h . Secondl y epoXy resi n (EPON834 )Was used as t he chai n eXtender t o react Wit h t he adduct of TETA- DGEPGi n P at 65 f or about 3 h . Then t he speci al phase i nversi on e mulsifi er Was used t