第四章 固体材料中敌履扩散.docVIP

第四章 固体材料中的扩散 Chapter4 The Diffusion in Solid Materials 作业1： Which type of diffusion do you think will be easier (have a lower activation energy)? a. C in HCP Ti b. N in BCC Ti c. Ti in BCC Ti Explain your choice. Solution: A and b are interstitial solid solutions, but c is a substitutional solid solution. So the mechanism of diffusion of a and b is interstitial diffusion, and the mechanism of diffusion of c is the vacancy exchange. We have known that the activation energy for vacancy-assisted diffusion Qv are higher than those for interstitional diffusion Qi. So c is the most difficult one. H