6-3等-202-7.1王代军-北京金属学会.doc

某巴西赤铁精矿配加蛇纹石制备氧化球团的性能研究 王代军 (北京首钢国际工程技术有限公司烧结设计室，北京 100043) 摘 要：以蛇纹石作为含镁添加剂，研究其对巴西赤铁矿球团成球性能、预热和焙烧性能影响。研究结果表明：随着蛇纹石配比加大，生球水分含量逐渐增加，生球的抗压强度提高，而落下强度和爆裂温度有所降低。预热球团抗压强度均呈先增加后降低的趋势，然后趋于平缓；焙烧球团的抗压强度均提高，但在焙烧温度为1280℃时，曲线变化规律最为明显。当蛇纹石配比一定时，随着预热温度的升高，预热球团和焙烧球团抗压强度均呈上升趋势。机理分析表明：配加蛇纹石可以促使固相扩散反应发生，提高球团矿固结强度；成品球团矿铁品位及还原度降低，还原膨胀率减小，软化开始温度升高，软化区间变窄，球团矿的高温冶金性能得到改善。 关键词：赤铁精矿；蛇纹石；预热；焙烧；??压强度 Preparation of Oxidized Pellets Performance by Adding Serpentine of a Brazilian Hematite Concentrate WANG Dai-jun (BeiJing ShouGang International Engineering Technology Co., Ltd. Beijing 100043, China) Abstract: The serpentine as magnesium additive, the ballability, preteat and roast performance of a Brazilian hematite concentrate are studied in this work. The results show that: with the increasing ratio of serpentine, the green ball moisture content is increased, the compressive strength is improved, but drop strength and burst temperature are reduced. The compressive strength of preheated pellets are increased first and then decreased, and then leveled off. The compressive strength of roasted pellets are all improved, especially when the roast temperature is 1280℃, the curve variation is most obviously. When the serpentine ratio is constant, with the preheating temperature increasing, the compressive strength of preheated and roasted pellets are all improved. Mechanism analysis shows: the solid phase reaction could be promoted with addition of serpentine, and the consolidation strength of pellets could be increased also. The iron grade and reduction of pellets are reduced, the reducing swelling is decreased, the softening begin temperature is raised, the softening range is narrowed, and the pyrometallurgical performance of pellets is improved. Key words: hematite concentrate, serpentine, preheat, roast, compressive strength 随着钢铁行业的迅猛发展，国内外适用于球团生产的优质磁铁精矿越来越少，许多钢铁企业不得不配加品质差的国内铁精矿，然而，这又有悖于高炉精料的发展方向；因此，我国铁矿石的供需矛盾日益突出[1]，采用赤铁精矿生产球团矿将成为一种趋势[2]。受矿石加工条件的制约，我国赤铁精矿品位较国外赤铁精矿低，而且粒度较粗，粒度粗又导致造球过程中膨润土的配加量增加，不仅