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基于源头提质的可燃固体废物热重燃烧动力学研究 PAGE 40 基于源头提质的可燃固体废物 热重燃烧动力学研究 学 院能源与环境学院专 业环境工程班 级学 号2008040403001姓 名胡慧指导教师李延吉负责教师李延吉 沈阳航空航天大学 2012年6月沈阳航空航天大学毕业设计（论文） PAGE 41 摘 要 随着社会经济的发展和人们生活水平的不断提高，能源和资源消耗量不断增加，城市生活垃圾已成为亟待解决的环境与社会问题。垃圾焚烧法因能快速有效地达到固体废物的资源化、无害化和减容化而是其他方式无可比拟的。但我国垃圾组分复杂多变，直接焚烧会产生二次污染而且浪费潜在的能源，因此垃圾源头分类越来越受重视。但我国人口众多垃??混合收集造成分类难，源头提质将垃圾分为干湿两类即可生物降解垃圾和可燃固体废物，居民容易接受。基于源头提质的可燃固体废物焚烧法具有二次污染少，燃烧效率高，能源转化率高的优势。 本课题通过热重差热分析仪研究基于源头提质的可燃固体废物的燃烧特性及其动力学研究，研究不同氯添加量、不同升温速率、不同氧浓度和添加CaO条件下对其燃烧特性的影响。实验结果表明：固体废弃物进行混合燃烧时，其燃烧特性可以由各组分单独的燃烧特性进行叠加而得到，某些混合试样的组分之间会表现出有相互影响，但一般说来并不强烈；混合垃圾中PVC、NaCl的含量增加时，燃烧的初始温度增加；升温速率和氧浓度的增大，可以提高失重速率，降低活化能；在三种不同的钙氯比条件下混合垃圾的燃烧过程均可看做两个一级反应，钙氯比为1时的活化能最小。 关键词：源头提质；可燃固体废物；热重燃烧特性；动力学 Combustion Characteristics and Kinetics of Combustible Solid Waste Based on Source Separation Abstract The problem of municipal solid waste has been paid increasing attention with the development of society and living standard of people. Combustion technology of waste is the best due to its reach reduction, harmless, recycling efficiently. However, the waste compositions are so complicated that may generate secondary pollution and waste potential resource if combust directly, the source separation is paid highly attention. Importantly, the source separation is difficult attributed to the large population in our country; consequently, Source quality and trash into dry and wet two types can be bio-degradable garbage and combustible solid waste, which residents easily accept. The combustion of combustible solid waste based on source separation according dry and wet waste shares the advantages of low secondary pollution, high combustion efficiency and source transformation rate. Consequently, this article studies the combustion characteristics and kinetics of combustible solid waste based on source separation, discusses the effects of chlorine source, addition of chlorine, heating rate, oxygen concentration and addition of CaO on combustion. T