含硫酸盐高浓度有机废水生物处理技术.pdfVIP

中国环境科学990322 中国环境科学 CHINA ENVIRONMENTAL SCIENCE 1999年　第19卷　第3期　Vol.19 No.3 1999 含硫酸盐高浓度有机废水生物处理技术 赵 毅　杨景亮　任洪强　罗人明　刘三学 摘要：采用硫酸盐还原—硫化物生物氧化—产甲烷—接触氧化工艺处理青霉素废水,硫 酸盐还原与有机物甲烷化分别在两个反应器中进行,有效地避免了硫酸盐还原菌对产甲 烷菌的竞争抑制;利用无色硫细菌将硫酸盐还原产物—硫化物氧化成S,消除了硫化物对 产甲烷菌的毒害作用.研究结果表明,当系统进水COD为4500～5000mg/L, 浓度为1500 ～1600mg/L时,系统出水中COD为310～348mg/L, COD平均去除率为93.2%, 平均去除 率为91.2%. 关键词：硫酸盐生物还原；硫化物生物氧化；产甲烷；接触氧化；青霉素废水 中图分类号：X703.1 文献标识码：A 文章编号：1000- 6923(1999)03- 0281- 04 A study on biological treatment technology for high strength sulfate— organic wastewater. ZHAO Yi1, YANG Jing-liang1, REN Hong-qiang1,LUO Ren-ming2, LIU San-xue2 (1.Department of Environmental Engineering, North China Electric Power University, Baoding 071003,China；2.Department of Environmental Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China). China Environmental Science. 1999,19(3)：281～284 Abstract：The penicillin wastewater was treated with the process of sulfate reduction—sulfide biological oxidation—methane production—contact oxidation. In this process, sulfate reduction was separated from methane production to avoid the inhibition on methane bacteria;and sulfide was oxidized by colorless sulfur bacteria to reduce poison its effect on methane bacteria. Experiment results showed:when the influent COD was 4500～5000mg/L and was l500～ 1600mg/L,the effluent COD of 310～348mg/L,COD average removal rate of 93.2％ and average removal rate of 91.2% were reached. Key words：sulfate biological reduction；sulfide biological oxidation；methane production； contact oxidation；penicillin wastewater 　　在轻工、制药等行业排放的生产废水中除含有高浓度有机物外,还含有高浓度硫酸 盐,此类废水属含硫酸盐高浓度有机废水.采用厌氧消化法进行处理,硫酸盐还原菌引起的 硫酸盐还原作用对厌氧消化产生严重的抑制影响.其影响机制综合起来可归纳为两个方 [1] 面 :一是硫酸盐还原菌和产甲烷菌都可以利用乙酸和H 2而产生基质竞争性抑制作用;二 file: