Multi-walled carbon nanotubes solid phase extraction of organophosphorus pesticide residues analysis.doc

 PAGE \* MERGEFORMAT 17 Multi-walled carbon nanotubes solid phase extraction of organophosphorus pesticide residues analysis Of: Zhao Xiang, Shi Wenli SUN Da-Jiang Wanghua Zhang Lianpeng Zhaomeng Bin Ding Mingyu [Abstract] established a multi-walled carbon nanotubes as adsorbent of solid-phase extraction and flame photometric detection gas chromatography vegetables, 16 kinds of organophosphorus pesticides in the method. With double-column dual-detector for qualitative and quantitative analysis. Established aqueous and organic phases like the two purification system. aqueous phase when the sample using sodium acetate, pH 5.0 acetate buffer system, vacuum pumping to remove water, dichloromethane as eluant, the recovery rate of only 9 pesticidesgt; 75% . for n-hexane dissolved drugs, acetone hexane (5:5, V / V) as eluent purification system, the organic phase, 16 pesticides recoveries weregt; 75%. The organic phase made use of sample purification system on cucumber, cabbage, leek, ginger and onion sample purification, the effect is good, that multi-walled carbon nanotubes have a strong adsorption capacity and removal of pigment, can overcome the interference pigments on the determination. [Key Words] multi-walled carbon nanotubes, solid phase extraction, organophosphorus pesticides, vegetables, gas chromatography flame photometric 1 Introduction Commonly used organophosphorus pesticides by gas chromatography flame photometric detection (GC / FPD) determination, FPD for the selective detector may purified vegetable samples is often directly into the sample analysis, the samples generally do not affect the determination of the pigment. However, the complex matrix sulfur-containing vegetables, usually using solid phase extraction (SFE) purifying [1], such as the use of Florisil SPE column purification. The darker the vegetable samples, Florisil SPE column after purification is still a certain color, will lead to the inlet, the column and detector conta