Nanoparticles prepared by supercritical drying and the catalyst for vinyl acetate vapor light detection.doc

 PAGE \* MERGEFORMAT 19 Nanoparticles prepared by supercritical drying and the catalyst for vinyl acetate vapor light detection Study: Caoxiao An Liu Yonghui PENG Ya-Li Wang [Abstract] using ethanol supercritical fluid drying (SCFD) (280 ℃ × 7.0 MPa × 30 min Preparation of nano MgO and Y2O3 particles, harmful gases found some catalysis luminous intensity is much higher than normal drying the nano MgO and Y2O3. SCFD technique to design a synthetic nano-MgO as sensitive materials, vinyl acetate catalyzed vapor light detection sensor. This sensor has high sensitivity and excellent selectivity, the temperature 279 ℃, wavelength 425 nm, air The flow rate was 160 mL / min under optimal conditions, the catalytic vapor light intensity and acetate concentration 1.8 ~ 1800 mg/m3 showed a good linear relationship within the detection limit of 0.7 mg/m3. When the same concentration of acetone, acetaldehyde, ethyl acetate, acetic acid, formaldehyde, ammonia, ethanol, benzene and methanol vapor through the sensor, in addition to the interference caused by ethanol, 3.56%, the other gases do not interfere with the basic determination of vinyl acetate. apply the method to quickly determine vinyl acetate in the air workshop. [Keywords:] Cataluminescence, MgO nano-materials, vinyl acetate, supercritical fluid drying, gas sensor Abstract MgO and Y2O3 nanoparticles were prepared by supercritical fluid drying (SCFD) method (280 ℃ × 7.0 MPa × 30 min). It was found that the cataluminescence (CTL) intensities of some harmful gases on MgO SCFD and Y2O3 SCFD nanoparticles were much higher than those on nanoparticles prepared by common drying (CD) method. A CTL sensor using MgO SCFD as the sensing material was developed for the detection of vinyl acetate vapor. The proposed sensor showed high sensitivity and selectivity to vinyl acetate under the optimal conditions of temperature of 279 ℃, wavelength of 425 nm and flow rate of 160 mL / min. The linear range of CTL intensity ve