Non-Aqueous Titration miniaturization of potassium citrate.doc

 PAGE \* MERGEFORMAT 7 Non-Aqueous Titration miniaturization of potassium citrate Author: Xie Yin Cong Shuang Cai Ling-Ling Wu Wei-bing Chen a first [Abstract] Determination of non-aqueous titration of potassium citrate, the operation is simple, rapid, and micro-titration conventional titration results were compared to the results obtained are very close, and both have good precision. [Keywords:] citrate potassium content in non-aqueous titration micro-experiment 1 Principle With glacial acetic acid as solvent, adding a certain amount of acetic anhydride to remove water. With crystal violet as indicator, with the determination of perchlorate standard solution of potassium citrate. 2 Reagents Glacial acetic acid (AR); acetic anhydride (AR); crystal violet indicator: 5g / L; perchlorate (AR): 0.1moL / L standard solution; potassium citrate (AR comply with HG 3  1297  80), potassium hydrogen phthalate (AR). Three main instruments Micro Burette (own research and development, patent No.:1); 50ml Burette acid; conical bottles (25ml; 250ml). 4 solution preparation HClO4  HAc (0.1mol * L-1): at 700 ~ 800mL of glacial acetic acid slowly adding 72% (mass ratio) of perchlorate 8.5mL, shaken, at room temperature slowly dropwise acetic anhydride 24mL, side bordered shake, plus finished even after Zhen Yao, cooling, plus an appropriate amount of anhydrous acetic acid, diluted to 1L, shake, placing 24h (so that the water solution of acetic anhydride with the full response). Of crystal violet indicator: 5g / L: 0.5g of crystal violet dissolved in 100mL glacial acetic acid solution. 5 0.1mol * L-1HClO4  HAc The calibration Micro-with the constant and non-aqueous titration of the same 0.1mol * L-1HClO4  HAc solution calibration. Conventional titration: Weigh accurately KHC8H4O4 0.4g ~ 0.5g in dry 250ml conical flask, add 50mL glacial acetic acid to dissolve, add a drop of crystal violet indicator, using HClO4  HAc (0.1mol * L-1) ease